in pentane byproducts: NaCl; Inert atm.; a suspn. of BiCl3 in pentane was added to a soln. of cyclophosphane in pentane at room temp.; ppt. was filtered;
in diethyl ether Irradiation (UV/VIS); precipitation of BiOCl and (after a longer period of time) Bi from an etheric BiCl3 solution during Raman spectroscopy;;
nitric acid or sodium hydrate in not given High Pressure; mixing Sb2O3 and Bi compd., under hydrothermal conditions, pH 1-9 (control by addn. of nitric acid or sodium hydrate); XRD;
in acetic anhydride Electrolysis; electrolysis of BiCl3 in acetic anhydride; formation of Cl2 corresponding to the calculated amount;;
参考文献
Schmidt, H.; Wittkopf, I.; Jander, G.
Z. Anorg. Chem., 1948 , vol. 256, p. 113 - 124
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Gmelin Handbook: Bi: SVol., 167, page 681 - 683
Seleznev, K. A.
Tr. po Khim. i Khim. Tekhnol., 1959 , vol. 2, # 3 p. 513 - 521
C. A., 1962 , vol. 57, p. 5562
Full Text Show Details
Gmelin Handbook: Pb: MVol.B1, 13.6.11, page 325 - 325
