water in water reaction on addn. of water inhibited in concd. NH4Cl- or alkali chloride solution;;
参考文献
Causse
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 112, p. 1220 - 1220
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Causse
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1891 , vol. 113, p. 547 - 547
H2; air in neat (no solvent) reaction of BiCl3 with H2 on heating at 300-310°C with formation of HCl and BiCl2; partially sublimation of BiCl3 with formation of BiOCl (in presence of air);; mixture of BiCl2, BiCl3 and BiOCl;;
参考文献
Montignie, E.
Bull. Soc. chim. France (5), 1937 , vol. 4, p. 588 - 591
in diethyl ether Irradiation (UV/VIS); precipitation of BiOCl and (after a longer period of time) Bi from an etheric BiCl3 solution during Raman spectroscopy;;
in water PH3 passed into a weak aq. acidic soln. of BiCl3; precipitate stored for 3 days over H2SO4;; Cl-content could not removed from the product by washing with concd. HCl;;