in ethylene glycol dimethyl ether
Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : NiBr2 : CuBr2 = 8 : 3 : 1; irradn. (254 nm) for 10 h gave deposition of Ni and Cu;
参考文献
Eisch, John J.; Shah, Jamshed H.; Boleslawski, Marek P.
Journal of Organometallic Chemistry, 1994 , vol. 464, # 1 p. 11 - 22
in ethylene glycol dimethyl ether
Irradiation (UV/VIS); under Ar; ratios B(3+) : Ni(2+) : Cu(2+) = 4 : 1 : 1; irradn. (254 nm) for 18 h gave deposition of Ni and Cu;
参考文献
Eisch, John J.; Shah, Jamshed H.; Boleslawski, Marek P.
Journal of Organometallic Chemistry, 1994 , vol. 464, # 1 p. 11 - 22
cyclopenta-1,3-diene in propan-1-ol
soln. of cyclopentadiene in PrOH added with stirring to soln. of CuBr2 in PrOH;
参考文献
Skumov, M. Ya.; Brailovskii, S. M.; Temkin, O. N.
Russian Chemical Bulletin, 2002 , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2002 , # 4 p. 572 - 579
cyclopenta-1,3-diene in butan-1-ol
soln. of cyclopentadiene in BuOH added with stirring to soln. of CuBr2 in BuOH;
参考文献
Skumov, M. Ya.; Brailovskii, S. M.; Temkin, O. N.
Russian Chemical Bulletin, 2002 , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2002 , # 4 p. 572 - 579
cyclopenta-1,3-diene in methanol
Kinetics; byproducts: trans-3,4-dimethoxy-1-cyclopentene, trans-3,5-dimethoxy-1-cyclopentene, cis-3,5-dimethoxy-1-cyclopentene; soln. of cyclopentadiene in MeOH added with stirring to soln. of CuBr2 in MeOH; reacted at 30-50°C for 20-70 min; CuBr, three dimethoxycyclopentene isomers and 3-methoxy-4-bromo-1-cyclopentene obtained;
参考文献
Skumov, M. Ya.; Brailovskii, S. M.; Temkin, O. N.
Russian Chemical Bulletin, 2002 , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2002 , # 4 p. 572 - 579
cyclopenta-1,3-diene in N,N-dimethyl-formamide; isopropyl alcohol
Kinetics; soln. of cyclopentadiene in DMF-i-PrOH added with stirring to soln. of CuBr2 in DMF-i-PrOH; reacted at 30°C;
参考文献
Skumov, M. Ya.; Brailovskii, S. M.; Temkin, O. N.
Russian Chemical Bulletin, 2002 , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 2002 , # 4 p. 572 - 579
