in sodium hydroxide oxidn. of Ru(IV)-nitrate in 1.0m NaOH soln. by KIO4 at 24°C;; extraction of RuO4 with CCl4;;
参考文献
Bezdek, M.; Mencl, J.
Collection of Czechoslovak Chemical Communications, 1965 , vol. 30, p. 711 - 723
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Gmelin Handbook: Ru: SVol., 38, page 84 - 86
Dengel, Andrew C.; Gibson, John F.; Griffith, William P.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 10 p. 2799 - 2800
water in water MoO3 and KIO4 were loaded in Parr 4749 PTFE-lined autoclave, water was added, the mixt. was heated for 3 d at 180°C; the autoclave was cooled at a rate of 9°C/h to 23°C, the mother liquors were decanted from crystalline products that were subsequently washed with methanol, the colorless plates of KMoO3(IO3) were sepd.from colorless cubes of KIO3;
参考文献
Sykora, Richard E.; Kang, Min Ok; Halasyamani, P. Shiv; Albrecht-Schmitt, Thomas E.
Journal of the American Chemical Society, 2002 , vol. 124, # 9 p. 1951 - 1957
