in neat (no solvent)
formation of PCl5 and I2 in the system PCl3#ICl; further react. forming PCl6I;;
参考文献
Fialkov, Ya. A.; Kuz'menko, A. A.
Zh. obshch. Khim., 1949 , vol. 19, p. 1645 - 1652
C. A., 1950 , p. 1354
Full Text Show Details
Gmelin Handbook: P: MVol.C, 231, page 529 - 530
in hydrogenchloride
react. of a soln. of NaH2PO2 and ICl in weakly acidic soln. (5 ml 0.1 n NaH2PO2 + 25 ml 0.1 n ICl in 0.4 n HCl) at ambient temp.;; 51.2 percent H3PO2 are oxidized after 0.5 h, 79.5 percent after 1 h, 97.9 percent after 3 h, 99.8 percent after 4 h;;
参考文献
Fialkov, Ya. F.; Kagan, F. E.
Zh. obshchei Khim., 1954 , vol. 24, p. 3 - 10
Full Text Show Details
Gmelin Handbook: P: MVol.C, 53, page 112 - 113
in sulfuric acid
dry N2-atmosphere; mixing equimolar amts. in 100 percent H2SO4 (room temp.); product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Dillon, Keith B.; Nisbet, Martin P.; Waddington, Thomas C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1591 - 1594
