反应条件
in diethyl ether byproducts: magnesium chloride, acetic acid; 1: addn. of soln. of carbonyl in ether to equimolar amts. of Bu3SnMgCl in ether, addn. of CH3COCl, reflux, under inert atmosphere, filtration, distn. in vac.; 2: mixt. warmed up to 200°C, then thermolysis in N2, condensation of; products in a dewar vessel (liquid N2), warmed up to ambient temp.; first reaction detected IR and NMR, purifn. of intermediate (acetate) by chromy. (Florisil, pentane);
参考文献
Duboudin, J. Georges; Ratier, Max; Trouve, Bruno
Journal of Organometallic Chemistry, 1987 , vol. 331, # 2 p. 181 - 192
