catalyst: HClO4 in water Kinetics; byproducts: HSO4(1-); acid catalysed hydrolysis of K-salt soln. at const. temp. 35, 30 and 25°C on mixing aliquots of component and catalyst solns. in sealed glass ampoule; microcalorimetric monitoring;
water in water hydrolysis in alkaline soln.;; only traces of sulfate or nitrogen formed; products of decompn. of hyponotrite observed; products of decompn. of hydroxylamine not observed;;
参考文献
Journal of the Chemical Society, , vol. 55, p. 760 - 773
Mg-amalgam in water byproducts: Mg(OH)2; 5 percent Mg amalgam, cooling with ice-NaCl mixture; storage in vac. over concd. H2SO4 for 20 day (NH2OH decomposes), makeing free from NaOH by washing with alcohol, drying in vac. desiccator;
Divers, E.
Journal of the Chemical Society, 1899 , vol. 75, p. 87 - 94
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Gmelin Handbook: N: MVol.4, 6.5, page 915 - 929
in N,N-dimethyl-formamide Electrolysis; bulk electrolysis of soln. containing NO, with CoTSPc-modified glassy carbon electrode, in the presence of TEAP as electrolyte, pH = 4-7; not isolated;
