in solid matrix In evapd. from Ta Knudsen cell heated to ca. 900°C, codeposited with an excess of PH3-doped Ar on a CsI window cooled to ca. 12 K for 2-3h, exposed to radiation with λ 436 nm, then 546 nm; not isolated, detected by IR;
tetrahydrofuran in tetrahydrofuran B4H10 dissolved in THF at -80°C, kept at 0°C for 4 h, treated with PH3 at -60°C, allowed to warm to 0°C, stored for67 h; NMR anal.;
in acetonitrile Kinetics; byproducts: HCl; react. in a shaken flow-type reactor (20-40°C);
参考文献
Dorfman, Ya. A.; Levina, L. V.; Polimbetova, G. S.; Emel'yanova, V. S.; Kel'man, I. V.; Karinskaya, A. S.
Sov. J. Coord. Chem. (Engl. Transl.), 1991 , vol. 17, p. 145 - 152
Koordinatsionnaya Khimiya, 1991 , vol. 17, p. 280 - 287
in acetonitrile Kinetics; continnous-flow apparatus, passge of PH3/Ar mixt.; gas chrommatographie anal.;
参考文献
Dorfman, Ya. A.; Levina, L. V.; Petrova, T. V.; Emel'yanova, V. S.; Polimbetova, G. S.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 1292 - 1293
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 1454 - 1455
