2-(N,N-dimethylamino)-pyridine; palladium (II) trifluoroacetate; oxygen; toluene-4-sulfonic acid in dimethyl sulfoxide T=80°C; P=760.051 Torr; 24 h;

lithium hydroxide; (.eta.6-1,4-dihydroxybenzene)(.eta.2,.eta.2-cyclooctadiene-1,5)rhodium tetrafluoroborate in ethylene glycol dimethyl ether; water T=50°C; 1 - 3 h; Product distribution / selectivity;

1: (4-fluoro-phenyl)-magnesium bromide With indium(III) chloride in tetrahydrofuran T=20°C; 0.5 h; 2: With water in tetrahydrofuran T=20°C; 0.166667 h; 3: cyclohexenon With [Rh(OH)(cycloocta-1,5-diene)]2 in tetrahydrofuran T=20°C; 6 h;

[Rh(OH)(cycloocta-1,5-diene)]2 in tetrahydrofuran T=35°C; 6 h;

lithium hydroxide; (.eta.6-1,4-dihydroxybenzene)(.eta.2,.eta.2-cyclooctadiene-1,5)rhodium tetrafluoroborate in ethylene glycol dimethyl ether; water T=50°C; 1 - 3 h; Product distribution / selectivity;

1: 1-bromo-4-fluorobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; Inert atmosphere; 2: With indium(III) chloride in tetrahydrofuran; hexane T=-78 - 20°C; 4 h; Inert atmosphere; 3: cyclohexenon With methanol; [RhCl(η2:η2-cycloocta-1,5-diene)]2; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in tetrahydrofuran; hexane T=110°C; Inert atmosphere;

chloroform; palladium diacetate; caesium carbonate; triphenylphosphine in toluene T=80°C; 24 h; Inert atmosphere;

[2,2']bipyridinyl; sulfuric acid; palladium diacetate in methanol T=60°C; Heck reaction; 15 h; Inert atmosphere;

Pd(OPiv)2; silver trifluoroacetate; tri-iso-propyl phosphine in 1,4-dioxane T=80°C; Buchwald-Hartwig Coupling; 24 h; Schlenk techniqueGloveboxInert atmosphereSealed tube;

vesicles(liposomes) of [3,5-didodecyl-2,6-bis{N-(4-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}methylphenyl)iminomethyl}phenyl]chloropalladium in water T=25°C; Miyaura-Michael reaction; 12 h; shaking;