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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
79044-27-2
合成路线
(共 5 条)
79044-27-2
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
+
18531-99-2
S-联萘酚
反应条件
Arthrobacter sp. lipase in aq. phosphate buffer; dimethyl sulfoxide T=25°C; pH=7; 44 h; Resolution of racemateEnzymatic reaction; SolventConcentration; enantioselective reaction;
参考文献
Gupta, Pankaj; Rouf, Abdul; Shah, Bhahwal Ali; Mahajan, Neha; Chaubey, Asha; Taneja, Subhash Chandra
Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 101, p. 35 - 39
79044-27-2
→
反应条件
123-86-4
乙酸丁酯
+
18531-94-7
R-1,1'-联-2-萘酚
反应条件
C4H9OH; lipase from Pseudomonas sp in di-isopropyl ether T=40°C; 91.2 h; Yield given;
参考文献
Agricultural and Biological Chemistry, , vol. 53, # 7 p. 1879 - 1884
79044-27-2
→
反应条件
18531-94-7
R-1,1'-联-2-萘酚
+
18531-99-2
S-联萘酚
反应条件
Arthrobacter sp. lipase in aq. phosphate buffer; dimethyl sulfoxide T=25°C; pH=7; 44 h; Resolution of racemateEnzymatic reaction; SolventConcentration; enantioselective reaction;
参考文献
Gupta, Pankaj; Rouf, Abdul; Shah, Bhahwal Ali; Mahajan, Neha; Chaubey, Asha; Taneja, Subhash Chandra
Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 101, p. 35 - 39
79044-27-2
→
反应条件
反应条件
Arthrobacter sp. lipase in aq. phosphate buffer; dimethyl sulfoxide T=25°C; pH=7; 24 h; Resolution of racemateEnzymatic reaction; enantioselective reaction;
参考文献
Gupta, Pankaj; Rouf, Abdul; Shah, Bhahwal Ali; Mahajan, Neha; Chaubey, Asha; Taneja, Subhash Chandra
Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 101, p. 35 - 39
79044-27-2
→
反应条件
79-20-9
乙酸甲酯
+
18531-94-7
R-1,1'-联-2-萘酚
+
602-09-5
1,1'-联-2-萘酚
反应条件
methanol; lipase from Pseudomonas sp in di-isopropyl ether T=40°C; 29.4 h; Yield given;
参考文献
Inagaki, Minoru; Hiratake, Jun; Nishioka, Takaaki; Oda, Jun'ichi
Agricultural and Biological Chemistry, 1989 , vol. 53, # 7 p. 1879 - 1884