7-氧代胆甾-5-烯-3-beta-基乙酸酯合成路线 （共 77 条）
反应条件
dihydrogen peroxide; molybdenum hexacarbonyl in acetonitrile 24 h; Heatingvar. solv: benzene; var. reag: EtOOH, i-PrOOH, t-BuOOH, cumene hydroperoxide; var. cat.: Fe(acac)3 or without cat.; Product distribution;
参考文献
Chemical & Pharmaceutical Bulletin, , vol. 28, # 6 p. 1836 - 1841
反应条件
pyridine; chromium trioxide-3,5-dimethylpyrazole
参考文献
Organic Mass Spectrometry, , vol. 17, # 6 p. 277 - 285
反应条件
ferric picolinate complexes; dihydrogen peroxide in acetonitrile 3 h; Ambient temperatureother 3β-acetoxy-Δ5-steroids; Mechanism;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 45, # 4 p. 750 - 752
参考文献
Journal of the American Chemical Society, , vol. 72, p. 1923,1929
Nature (London, United Kingdom), , vol. 164, p. 317
反应条件
in acetonitrile 24 h; Heatingvar. solv., reag; add of cat.;
参考文献
Chemical & Pharmaceutical Bulletin, , vol. 28, # 6 p. 1836 - 1841
反应条件
tert.-butylhydroperoxide; 5,10,15,20-tetrakisphenylporphyrinatoiron(III) chloride in chlorobenzene T=25°C; 1 h; various peroxide systems, concns. and temp.; MechanismProduct distribution;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 35, # 6 p. 2177 - 2183
反应条件
tert.-butylhydroperoxide; ruthenium trichloride in cyclohexane; water T=15 - 20°C; 24 h; various solvents, further steroids; Product distributionMechanism;
参考文献
Tetrahedron Letters, , vol. 37, # 20 p. 3429 - 3432
反应条件
iron (III) acetylacetonate in benzene Heatingother oxidant, other solvents, other catalysts; Product distribution;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 31, # 4 p. 1166 - 1171
参考文献
Journal of Organic Chemistry, , vol. 1, p. 490,494
反应条件
T=97°C; nach 40 min;
参考文献
Journal of the Chemical Society, , p. 759
