methyl bromide in diethyl ether
byproducts: MePhEtSiH; EtLi and MeBr in ether were added dropwise to an equimolar amt. of silane, room temp., N2 atm.; hydrolysis, extn. (ether), evapn., not sep., detected with NMR spectra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
methyl bromide in diethyl ether
byproducts: MePhEtSiOMe; EtLi and MeBr in ether were added dropwise to an equimolar amt. of silane, room temp., N2 atm.; hydrolysis, extn. (ether), evapn., not sep., detected with NMR spectra and GLC;
参考文献
Corriu, R. J. P.; Ould-Kada, S.; Lanneau, G. F.
Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 39 - 50
Burgers, Peter C.; Holmes, John L.; Mommers, Alexander A.; Szulejko, Jan E.
Journal of the American Chemical Society, 1984 , vol. 106, # 3 p. 521 - 524
tert.-butylhydroperoxide in tetrahydrofuran; hexane; benzene
T=-78 - -20°C; 3 h;
参考文献
Meth-Cohn, Otto; Moore, Clive; Taljaard, Heinrich C.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 2663 - 2674
