(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
tetramethyl-ammonium fluoride in ethylene glycol dimethyl ether T=-60 - 20°C;
参考文献
Kirij, Nataliya V.; Yagupolskii, Yurii L.; Petukh, Nataliya V.; Tyrra, Wieland; Naumann, Dieter
Tetrahedron Letters, 2001 , vol. 42, # 46 p. 8181 - 8183
反应条件
1: (trifluoromethyl)-trimethylsilane With silver fluoride in N,N-dimethyl-formamide T=20°C; 0.333333 h; 2: With copper in N,N-dimethyl-formamide 4 h; 3: pentafluorophenyl iodide in N,N-dimethyl-formamide T=50°C; 3 h;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Yagupolskii, Yurii L.; Naumann, Dieter; Moeller, Angela
Journal of Fluorine Chemistry, 2012 , vol. 133, p. 67 - 71
反应条件
di-tert-butyl peroxide; sodium acetate; sodium t-butanolate in 1,2-dichloro-ethane T=80°C; 3 h; Inert atmosphere;
参考文献
Chu, Lingling; Qing, Feng-Ling
Journal of the American Chemical Society, 2012 , vol. 134, # 2 p. 1298 - 1304
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran T=-10°C; 1 h;
参考文献
Synlett, , # 3 p. 379 - 381
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran T=-10°C; 1 h;
参考文献
Synlett, , # 3 p. 379 - 381
反应条件
cesium fluoride in acetonitrile T=20°C; 15 h;
参考文献
Eisenberger, Patrick; Gischig, Sebastian; Togni, Antonio
Chemistry - A European Journal, 2006 , vol. 12, # 9 p. 2579 - 2586
反应条件
in ethylene glycol dimethyl ether T=-40 - 0°C; 6.5 h;
参考文献
Pavlenko, Natalya V.; Babadzhanova, Lesya A.; Gerus, Igor I.; Yagupolskii, Yurii L.; Tyrra, Wieland; Naumann, Dieter
European Journal of Inorganic Chemistry, 2007 , # 11 p. 1501 - 1507
反应条件
titanium tetrachloride T=-20 - 20°C; Inert atmosphere;
参考文献
Levin, Vitalij V.; Dilman, Alexander D.; Belyakov, Pavel A.; Struchkova, Marina I.; Tartakovsky, Vladimir A.
Journal of Fluorine Chemistry, 2009 , vol. 130, # 7 p. 667 - 670
反应条件
sodium iodide in tetrahydrofuran T=65°C; 2 h; Inert atmosphereSchlenk technique;
参考文献
Lee, Graham M.; Harrison, Daniel J.; Korobkov, Ilia; Tom Baker
Chemical Communications, 2014 , vol. 50, # 9 p. 1128 - 1130
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran; toluene 18 h; Ambient temperature;
参考文献
Wiedemann, Juergen; Heiner, Thomas; Mloston, Gregorz; Prakash, G.K. Surya; Olah, George A.
Angewandte Chemie - International Edition, 1998 , vol. 37, # 6 p. 820 - 821
