(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
potassium fluoride; potassium phosphate; copper(l) iodide; 1,10-phenanthroline in N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Organic Letters, , vol. 12, # 21 p. 5060 - 5063
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper(l) chloride in N,N-dimethyl-formamide T=70°C; 4 h;
参考文献
Organic Letters, , vol. 12, # 21 p. 5060 - 5063
反应条件
1,10-phenanthroline; Cu(OH)2; potassium carbonate in 1,2-dichloro-ethane T=50°C; 36 h;
参考文献
Chu, Lingling; Qing, Feng-Ling
Synthesis, 2012 , vol. 44, # 10 p. 1521 - 1525
反应条件
1: (trifluoromethyl)-trimethylsilane With silver fluoride in N,N-dimethyl-formamide T=20°C; 0.333333 h; 2: With copper in N,N-dimethyl-formamide 4 h; 3: 2-bromo-pyrimidine in N,N-dimethyl-formamide T=20°C; 12 h;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Yagupolskii, Yurii L.; Naumann, Dieter; Moeller, Angela
Journal of Fluorine Chemistry, 2012 , vol. 133, p. 67 - 71
反应条件
1: (trifluoromethyl)-trimethylsilane With silver monofluoride T=20°C; 2 h; 2: 2-fluoro-benzoyl chloride With 4-(N,N-dimethlyamino)pyridine in dichloromethane T=20°C; 48 h; Further stages.;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Naumann, Dieter; Fischer, Hendrik T.M.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1385 - 1389
反应条件
[Bu4N]+[(MeO)2P(O)O]- in N,N-dimethyl-formamide T=20°C; 2 h;
参考文献
Prakash, G.K. Surya; Panja, Chiradeep; Vaghoo, Habiba; Surampudi, Vijayalakshmi; Kultyshev, Roman; Mandal, Mihirbaran; Rasul, Golam; Mathew, Thomas; Olah, George A.
Journal of Organic Chemistry, 2006 , vol. 71, # 18 p. 6806 - 6813
反应条件
1,10-phenanthroline; oxygen; copper diacetate; cesium fluoride in iso-butyronitrile T=20°C; Chan-Lam-type reaction; P=760.051 Torr; 1 h; Molecular sieveInert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 4 p. 1174 - 1176
反应条件
copper diacetate; triethylamine; cesium fluoride in 1,2-dichloro-ethane T=20°C; Chan-Lam-type reaction; P=760.051 Torr; Molecular sieveInert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 4 p. 1174 - 1176
反应条件
1,10-phenanthroline; oxygen; cesium fluoride; copper dichloride in 1,2-dichloro-ethane T=20°C; Chan-Lam-type reaction; P=760.051 Torr; Molecular sieveInert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 4 p. 1174 - 1176
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Ye, Yingda; Lee, Shin Hee; Sanford, Melanie S.
Organic Letters, 2011 , vol. 13, # 20 p. 5464 - 5467
