(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
potassium fluoride; 1,10-phenanthroline; copper diacetate; silver carbonate in N,N-dimethyl-formamide
T=100°C; ConcentrationReagent/catalystSolvent;
参考文献
Fu, Dan; Zhang, Jian; Cao, Song
Journal of Fluorine Chemistry, 2013 , vol. 156, p. 170 - 176
反应条件
potassium fluoride; copper(l) iodide; 1,10-phenanthroline; silver carbonate in N,N-dimethyl-formamide
T=100°C; ConcentrationReagent/catalystSolvent;
参考文献
Fu, Dan; Zhang, Jian; Cao, Song
Journal of Fluorine Chemistry, 2013 , vol. 156, p. 170 - 176
反应条件
1: With potassium carbonate in N,N-dimethyl-formamide
T=20°C; 4 h;
2: With water in N,N-dimethyl-formamide
4 h; Acidic conditions;
参考文献
Cheng, Huicheng; Pei, Yu; Leng, Faqiang; Li, Jingya; Liang, Apeng; Zou, Dapeng; Wu, Yangjie; Wu, Yusheng
Tetrahedron Letters, 2013 , vol. 54, # 33 p. 4483 - 4486
反应条件
boron tribromide in dichloromethane
T=15°C; 0.0333333 h; Inert atmosphere;
参考文献
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5
反应条件
tetra-n-butylammonium difluorotriphenylsilicate(IV) in tetrahydrofuran
T=0 - 10°C; 4 h; Inert atmosphere;
参考文献
Masusai, Chonticha; Soorukram, Darunee; Kuhakarn, Chutima; Tuchinda, Patoomratana; Reutrakul, Vichai; Pohmakotr, Manat
Journal of Fluorine Chemistry, 2013 , vol. 154, p. 37 - 42
参考文献
LIGAND PHARMACEUTICALS INCORPORATED
Patent: WO2009/82437 A2, 2009 ;
Location in patent: Page/Page column 145 ;
反应条件
1: With potassium carbonate in N,N-dimethyl-formamide
T=20°C; 4 h;
2: With water in N,N-dimethyl-formamide
4 h; Acidic conditions;
参考文献
Cheng, Huicheng; Pei, Yu; Leng, Faqiang; Li, Jingya; Liang, Apeng; Zou, Dapeng; Wu, Yangjie; Wu, Yusheng
Tetrahedron Letters, 2013 , vol. 54, # 33 p. 4483 - 4486
反应条件
[Pd(η3-1-Ph-allyl)(μ-Cl)]2; cyclohexyl BrettPhos; sodium lauryl sulfate; cesium fluoride in toluene
T=110°C; Inert atmosphere;
参考文献
Samant, Bhupesh S.; Kabalka, George W.
Chemical Communications, 2011 , vol. 47, # 25 p. 7236 - 7238
反应条件
copper(l) iodide; silver fluoride; sodium t-butanolate; N-methyl-2-(methylamino)ethylamine in 1-methyl-pyrrolidin-2-one
T=20 - 90°C; 5.5 h; Inert atmosphere;
参考文献
Weng, Zhiqiang; Lee, Richmond; Jia, Weiguo; Yuan, Yaofeng; Wang, Wenfeng; Feng, Xue; Huang, Kuo-Wei
Organometallics, 2011 , vol. 30, # 11 p. 3229 - 3232
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane
T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Ye, Yingda; Lee, Shin Hee; Sanford, Melanie S.
Organic Letters, 2011 , vol. 13, # 20 p. 5464 - 5467
