(三氟甲基)三甲基硅烷合成路线 （共 455 条）
反应条件
potassium fluoride; copper(l) iodide; 1,10-phenanthroline in N,N-dimethyl-formamide
T=100°C; 6 h;
参考文献
Chu, Lingling; Qing, Feng-Ling
Journal of the American Chemical Society, 2010 , vol. 132, # 21 p. 7262 - 7263
反应条件
potassium fluoride; potassium phosphate; 1,10-phenanthroline; copper (I) trifluoromethane sulfonate benzene; silver carbonate in N,N-dimethyl-formamide
T=45°C; Inert atmosphere;
参考文献
Chu, Lingling; Qing, Feng-Ling
Organic Letters, 2010 , vol. 12, # 21 p. 5060 - 5063
反应条件
potassium fluoride; silver trifluoromethanesulfonate in 1,2-dichloro-ethane
T=85°C; 24 h; Inert atmosphereDarkness;
参考文献
Ye, Yingda; Lee, Shin Hee; Sanford, Melanie S.
Organic Letters, 2011 , vol. 13, # 20 p. 5464 - 5467
反应条件
[Bu4N]+[(MeO)2P(O)O]- in N,N-dimethyl-formamide
T=20°C; 1 h;
参考文献
Prakash, G.K. Surya; Panja, Chiradeep; Vaghoo, Habiba; Surampudi, Vijayalakshmi; Kultyshev, Roman; Mandal, Mihirbaran; Rasul, Golam; Mathew, Thomas; Olah, George A.
Journal of Organic Chemistry, 2006 , vol. 71, # 18 p. 6806 - 6813
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
0 deg C, 5 min then rt., 2.5 h;
参考文献
Billard, Thierry; Large, Sylvie; Langlois, Bernard R.
Tetrahedron Letters, 1997 , vol. 38, # 1 p. 65 - 68
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran; dichloromethane
18 h; Ambient temperature;
参考文献
Wiedemann, Juergen; Heiner, Thomas; Mloston, Gregorz; Prakash, G.K. Surya; Olah, George A.
Angewandte Chemie - International Edition, 1998 , vol. 37, # 6 p. 820 - 821
反应条件
1: (trifluoromethyl)-trimethylsilane With silver monofluoride
T=20°C; 2 h;
2: 4-nitro-benzoyl chloride With 4-(N,N-dimethlyamino)pyridine in dichloromethane
T=20°C; 72 h; Further stages.;
参考文献
Kremlev, Mikhail M.; Mushta, Aleksej I.; Tyrra, Wieland; Naumann, Dieter; Fischer, Hendrik T.M.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 11 p. 1385 - 1389
反应条件
potassium fluoride; copper(l) iodide in 1-methyl-pyrrolidin-2-one
T=50°C; 20 h;
参考文献
Cottet, Fabrice; Marull, Marc; Lefebvre, Olivier; Schlosser, Manfred
European Journal of Organic Chemistry, 2003 , # 8 p. 1559 - 1568
反应条件
potassium fluoride; copper(l) iodide in 1-methyl-pyrrolidin-2-one
T=50°C; 20 h;
参考文献
Cottet, Fabrice; Marull, Marc; Lefebvre, Olivier; Schlosser, Manfred
European Journal of Organic Chemistry, 2003 , # 8 p. 1559 - 1568
反应条件
1,10-phenanthroline; oxygen; copper diacetate; cesium fluoride in iso-butyronitrile
T=20°C; Chan-Lam-type reaction; P=760.051 Torr; 3 h; Molecular sieveInert atmosphere;
参考文献
Senecal, Todd D.; Parsons, Andrew T.; Buchwald, Stephen L.
Journal of Organic Chemistry, 2011 , vol. 76, # 4 p. 1174 - 1176
