2-甲基-1-丁烯-3-酮合成路线 （共 116 条）
反应条件
(i) dioxane, (ii) NaOAc, aq. AcOH; Multistep reaction;
参考文献
Stork,G. et al.
Journal of the American Chemical Society, 1963 , vol. 85, p. 207 - 222
反应条件
potassium hydroxide; ethanol
参考文献
Colonge et al.
Bulletin de la Societe Chimique de France, 1954 , p. 1404,1406
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Bergmann et al.
Bulletin de la Societe Chimique de France, 1957 , p. 290,291
参考文献
Colonge et al.
Bulletin de la Societe Chimique de France, 1954 , p. 1404,1406
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride
参考文献
Barlet,R.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1974 , vol. 278, p. 621 - 624
反应条件
1: acetic acid; sodium azide / water 2: triphenylphosphine / tetrahydrofuran / 3.9 h / 20 °C / |Reflux; |Cooling with ice 3: ammonia / acetonitrile; water / 1.16 h / 20 °C / |Cooling with ice 4: dimethylsulfoxide-d6 / 20 °C View Scheme
参考文献
Fesenko, Anastasia A.; Dem'Yachenko, Ekaterina A.; Fedorova, Galina A.; Shutalev, Anatoly D.
Monatshefte fur Chemie, 2013 , vol. 144, # 3 p. 351 - 359
反应条件
1: hydroxylamine hydrochloride; sodium carbonate / methanol / 1 h / 65 °C / |Inert atmosphere 2: triethylamine / dichloromethane / 0 °C / |Inert atmosphere 3: silver(I) acetate; [{(η5-C5Me5)RhCl}2(μ-Cl)2] / 1,2-dichloro-ethane; acetic acid / 14 h / 85 °C / |Inert atmosphere View Scheme
参考文献
Neely, Jamie M.; Rovis, Tomislav
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 66 - 69
反应条件
1: bromine / 0 °C 2: diethyl ether 3: PtO2 / Hydrogenation View Scheme
参考文献
Wagner
Journal of the American Chemical Society, 1949 , vol. 71, p. 3216
反应条件
ethanol; nickel T=80°C; P=73550.8 Torr; Hydrogenation;
参考文献
McMahon et al.
Journal of the American Chemical Society, 1948 , vol. 70, p. 2976
反应条件
T=80°C; P=77228.3 Torr; Hydrogenation;
参考文献
McMahon et al.
Journal of the American Chemical Society, 1948 , vol. 70, p. 2976
反应条件
T=20 - 32°C; P=55163.1 Torr; Hydrogenation;
参考文献
McMahon et al.
Journal of the American Chemical Society, 1948 , vol. 70, p. 2976
