2,2,4,4-四甲基-3-戊酮合成路线 (共 175 条)
反应条件
in diethyl ether T=25°C; 1 h; effects of salts (MeOK, PhCH2OK, (Me2NCH2)2CHOK, MeONa, t-BuOLi, Bu4NBr, BzlEt3NCl); Product distribution;
参考文献
Richey, Herman G.; DeStephano, Joseph P.
Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3281 - 3286
反应条件
in diethyl ether T=25°C; 1 h; effects of salts (MeOK, t-BuOLi), other reaction time: 24 h; Product distribution;
参考文献
Richey, Herman G.; DeStephano, Joseph P.
Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3281 - 3286
反应条件
potassium tert-butylate T=185°C;
参考文献
Dyllick-Brenzinger, Rainer A.; Patel, Vijay; Rampersad, Mollin B.; Stothers, J. B.; Thomas, Shirley E.
Canadian Journal of Chemistry, 1990 , vol. 68, # 7 p. 1106 - 1115
反应条件
Michlers ketone or fenchone or diphenylketene in neat (no solvent) byproducts: H2; at 156-240°C;;
参考文献
Gmelin Handbook: Na: SVol.4, 5, page 1379 - 1380
参考文献
Freidlin; Lebedewa
Zhurnal Obshchei Khimii, 1939 , vol. 9, p. 1589,1593
Chem. Zentralbl., 1941 , vol. 112, # I p. 511
反应条件
sodium amide T=220°C;
参考文献
Freidlin; Lebedewa
Zhurnal Obshchei Khimii, vol. 9, p. 1592
Chem. Zentralbl., 1941 , vol. 112, # I p. 511
反应条件
in benzene-d6 T=31.9°C; Irradiation;
参考文献
Lehr, Gary F.; Turro, Nicholas J.
Tetrahedron, 1981 , vol. 37, # 19 p. 3411 - 3420
反应条件
in water-d2 T=31.9°C; Irradiation;
参考文献
Lehr, Gary F.; Turro, Nicholas J.
Tetrahedron, 1981 , vol. 37, # 19 p. 3411 - 3420
反应条件
in octane T=25°C; P=25840 Torr; 1 h; Irradiationvar. of pressure, viscosity dependence from pressure; Product distributionMechanismKinetics;
参考文献
Costello, Andrew R.; Lindsay Smith, John R.; Stark, Moray S.; Waddington, David J.
Journal of the Chemical Society - Faraday Transactions, 1996 , vol. 92, # 19 p. 3497 - 3507
反应条件
in N-dodecane T=30°C; 0.5 h; Irradiationalso in other solvents (solvent viscosity dependence); Product distribution;
参考文献
Tanner, Dennis D.; Rahimi, Parviz M.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 225 - 229