2,2,4,4-四甲基-3-戊酮合成路线 （共 175 条）
反应条件
1: 4-tert-butyl-4-hydroxy-2,2,5,5-tetramethylhexan-3-one With n-butyllithium in hexane; pentane T=-40°C; 2: 2,4-dimethylpentan-3-one in hexane; pentane T=-40 - 20°C;
参考文献
Chemistry - A European Journal, , vol. 18, # 24 p. 7506 - 7515
反应条件
1: 75 percent / 5-methyl-2-chloro-3-phenyl-2,3-dihydro-1,3,4,2-oxadiazaphosphole, pyridine / Ambient temperature 2: 73 percent / tetrahydrofuran / 0.5 h / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 52, # 45 p. 14297 - 14310
反应条件
lithium aluminium tetrahydride; titanium(III) chloride T=80°C; 96 h;
参考文献
Liebigs Annales, , # 1 p. 193 - 202
反应条件
1: 63 percent / Na / diethyl ether / 1.) reflux, 0.5 h, 2.) r.t., overnight 2: 45 percent / diethyl ether; pentane 3: 95 percent / diethyl ether / Ambient temperature 4: 1.) 220 deg C, 10 min, 2.) 230-240 deg C, 5 min View Scheme
参考文献
Liebigs Annales, , # 1 p. 193 - 202
反应条件
1: 45 percent / diethyl ether; pentane 2: 95 percent / diethyl ether / Ambient temperature 3: 1.) 220 deg C, 10 min, 2.) 230-240 deg C, 5 min View Scheme
参考文献
Liebigs Annales, , # 1 p. 193 - 202
反应条件
1: 1.) 220 deg C, 10 min, 2.) 230-240 deg C, 5 min 2: LiAlH4, TiCl3 / tetrahydrofuran / 6 h / 75 °C / Irradiation View Scheme
参考文献
Liebigs Annales, , # 1 p. 193 - 202
反应条件
1: n-butyllithium / benzene / 0.25 h / Cooling with ice 2: benzene / 60 h View Scheme
参考文献
Chemistry - A European Journal, , vol. 18, # 24 p. 7506 - 7515
反应条件
N-(1,1-dimethylethyl)sulfamoyl chloride; triethylamine in diethyl ether 0.75 h;
参考文献
Chemische Berichte, , vol. 114, # 2 p. 774 - 786
反应条件
3-diazo-2,2,4,4-tetramethylpentane; triethylamine in diethyl ether 0.75 h; further reagent: 2-diazo-3,3-dimethylbutane;
参考文献
Chemische Berichte, , vol. 114, # 2 p. 774 - 786
反应条件
triethylamine in diethyl ether 0.75 h;
参考文献
Chemische Berichte, , vol. 114, # 2 p. 774 - 786
