2,2,4,4-四甲基-3-戊酮合成路线 （共 175 条）
反应条件
tert-butoxyl radical in tetrachloromethane T=130°C; further temperature; Product distribution;
参考文献
Lindsay, D. A.; Lusztyk, J.; Ingold, K. U.
Journal of the American Chemical Society, 1984 , vol. 106, # 23 p. 7087 - 7093
反应条件
in nujol T=30°C; Irradiation; Product distribution;
参考文献
Tanner, Dennis D.; Rahimi, Parviz M.
Journal of the American Chemical Society, 1982 , vol. 104, # 1 p. 225 - 229
反应条件
T=30°C; bei verschiedener Konzentration (83.6prozent bis 96.1prozent H2SO4); Rate constant;
参考文献
Zook et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 4436
反应条件
1: sulfuric acid 2: alkaline aqueous sodium hypochlorite / zuletzt bei 90grad View Scheme
参考文献
Petrov,A.D. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1960 , vol. 30, p. 363 - 369,387 - 392
反应条件
1: 60 percent / hydroxylamine hydrochloride, 15percent aq. NaOH / aq. ethanol / 120 h / Heating 2: 43 percent / nitrosyl chloride / tetrahydrofuran; pyridine / 2.5 h / -20 °C 3: 73 percent / ammonia / tetrahydrofuran / 4 h / 0 °C View Scheme
参考文献
Guziec, Frank S.; Russo, Joseph M.
Synthesis, 1984 , # 6 p. 479 - 481
反应条件
2: SOCl2 / pyridine 3: (i) NaBH4, AlCl3, diglyme, (ii) NaOH, aq. H2O2, EtOH 4: H2SO4, AcOH, CrO3, H2O 5: SOCl2 View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
anschliessenden Erhitzen mit wss.Natronlauge; anderen Produkte:tert-Butylamin; Pivalinsaeure; 1-tert-Butyl-3-methyl-benzol;
参考文献
Zook; Paviak
Journal of the American Chemical Society, 1955 , vol. 77, p. 2501
反应条件
N,O-bis(trimethylsilyl)hydroxylamine; potassium hydride in tetrahydrofuran 15 h; Heating- 78 deg C to room temp.;
参考文献
Hoffman, Robert V.; Buntain, Gregory A.
Synthesis, 1987 , # 9 p. 831 - 833
反应条件
T=75°C; P=4854350 Torr; Rate constant;
参考文献
Jones et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 2151,2153
反应条件
Michlers ketone or fenchone or diphenylketene in neat (no solvent) byproducts: H2; at 156-240°C;;
参考文献
Gmelin Handbook: Na: SVol.4, 5, page 1379 - 1380
