(2-溴代烯丙基)三甲硅烷合成路线 （共 17 条）
反应条件
tert.-butyl lithium; benzyl bromide; zinc(II) chloride; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; diethyl ether; pentane
1.) r.t., 2 h, 2.) -15 deg C, 15 min; Yield given. Yields of byproduct given;
参考文献
Eshelby, James J.; Parsons, Philip J.; Crowley, Patrick J.
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 2 p. 191 - 199
反应条件
tert.-butyl lithium; zinc(II) chloride; tetrakis(triphenylphosphine) palladium(0)
1.) Et2O, pentane, r.t., 2 h, 2.) Et2O, -15 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Eshelby, James J.; Parsons, Philip J.; Crowley, Patrick J.
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 2 p. 191 - 199
反应条件
tetrakis (triphenylphosphine) palladium (0) in tetrahydrofuran; water; benzene
参考文献
Merck and Co., Inc.
Patent: US6083980 A1, 2000 ;
反应条件
titanium tetrachloride in dichloromethane
-78 deg C, 2 h -> 0 deg C;
参考文献
Trost, Barry M.; Coppola, Brian P.
Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6879 - 6881
反应条件
titanium tetrachloride in dichloromethane
-78 deg C, 2 h -> 0 deg C;
参考文献
Trost, Barry M.; Coppola, Brian P.
Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6879 - 6881
反应条件
[1,4-bis-(diphenylphosphine)butane]palladium (II) dichloride in diethyl ether
1 h; Heating0 deg C,then reflux;
参考文献
Minato, Akio; Suzuki, Keizo
Tetrahedron Letters, 1984 , vol. 25, # 1 p. 83 - 86
反应条件
[1,4-bis-(diphenylphosphine)butane]palladium (II) dichloride in diethyl ether
1 h; Heating0 deg C,then reflux;
参考文献
Minato, Akio; Suzuki, Keizo
Tetrahedron Letters, 1984 , vol. 25, # 1 p. 83 - 86
