2-乙酰氨基-2-脱氧-4-O-(beta-D-吡喃半乳糖基)-D-吡喃半乳糖合成路线 （共 3 条）
→
72142-81-5N-[(2R,3R,4R,5R)-3,4,5-三羟基-1-氧代-6-[(2R,3R,4S,5R,6R)-3,4,5-三羟基-6-(羟基甲基)四氢吡喃-2-基]氧基己烷-2-基]乙酰胺+
反应条件
diethylphosphoric acid ethyl ester; sodium acetate; β-galactosidase in water
T=30°C; galactosylation; Enzymatic reaction;
参考文献
Jones, Christopher; Previato, Jose O.; Mendonca-Previato
Carbohydrate Research, 2000 , vol. 328, # 3 p. 321 - 330
反应条件
mercury(II) cyanide; benzene
Erwaermen des Reaktionsprodukts mit wss. Essigsaeure und Behandeln mit wss. Natronlauge;
参考文献
Masamune et al.
Tohoku Journal of Experimental Medicine, 1956 , vol. 65, p. 157,161, 162
→
72142-81-5N-[(2R,3R,4R,5R)-3,4,5-三羟基-1-氧代-6-[(2R,3R,4S,5R,6R)-3,4,5-三羟基-6-(羟基甲基)四氢吡喃-2-基]氧基己烷-2-基]乙酰胺+
反应条件
phosphate buffer; β-galactosidase in N,N-dimethyl-formamide
T=37°C; pH=6.0; Product distribution; Further Variations:Reagents;
参考文献
Miyasato, Mariko; Ajisaka, Katsumi
Bioscience, Biotechnology and Biochemistry, 2004 , vol. 68, # 10 p. 2086 - 2090
