1,2,3,4,6-alpha-D-葡萄糖五乙酸酯合成路线 （共 153 条）
反应条件
1: HBr; acetic acid / CH2Cl2 / 2.5 h / 20 °C 2: Et3N; Bu4NBr / 1,2-dichloro-ethane / 16 h / 75 °C View Scheme
参考文献
Dong, Li; Roosenberg II, John M.; Miller, Marvin J.
Journal of the American Chemical Society, 2002 , vol. 124, # 50 p. 15001 - 15005
反应条件
1.1: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C / Inert atmosphere 2.1: methanol; sodium methylate / 20 °C 2.2: Amberlite.(R). IR-120 H+ ion exchange 3.1: sodium hydride / N,N-dimethyl-formamide / 2.5 h / 0 - 20 °C / Inert atmosphere 3.2: 12 h / 20 °C / Inert atmosphere 4.1: N-bromosuccinmide; water / acetone / 3 h / 20 °C View Scheme
参考文献
Lambu, Mallikharjuna Rao; Hussain, Altaf; Sharma, Deepak K.; Yousuf, Syed Khalid; Singh, Baldev; Tripathi, Anil. K.; Mukherjee, Debaraj
RSC Advances, 2014 , vol. 4, # 22 p. 11023 - 11028
反应条件
boron trifluoride diethyl etherate in dichloromethane 2 h; Heating;
参考文献
Sofia, Michael J.; Kakarla, Ramesh; Kogan, Natan; Dulina, Richard; Hui; Hatzenbuhler, Nicole T.; Liu, Dashan; Chen, Anna; Wagler, Thomas
Bioorganic and Medicinal Chemistry Letters, 1997 , vol. 7, # 17 p. 2251 - 2254
反应条件
zinc(II) iodide in dichloromethane T=20°C; 2 h; Inert atmosphere;
参考文献
Tran, Anh-Tuan; Burden, Richard; Racys, Daugirdas T.; Carmen Galan
Chemical Communications, 2011 , vol. 47, # 15 p. 4526 - 4528
反应条件
1: pyridine; hydrogen fluoride / -20 - 20 °C 2: methanol; sodium methylate / 20 °C 3: sodium hydroxide; Thermus nonproteolyticus HG102 E338A mutant; glycine / aq. buffer / 48 h / 45 °C / pH 8.8 / |Enzymatic reaction View Scheme
参考文献
Wei, Jinhua; Lv, Xun; Lue, Yang; Yang, Gangzhu; Fu, Lifeng; Yang, Liu; Wang, Jianjun; Gao, Jianhui; Cheng, Shuihong; Duan, Qian; Jin, Cheng; Li, Xuebing
European Journal of Organic Chemistry, 2013 , # 12 p. 2414 - 2419
反应条件
boron trifluoride diethyl etherate in dichloromethane T=20°C; 8 h;
参考文献
Dasgupta, Somnath; Rajput, Vishal Kumar; Roy, Bimalendu; Mukhopadhyay, Balaram
Journal of Carbohydrate Chemistry, 2007 , vol. 26, # 2 p. 91 - 106
反应条件
1.1: tin(IV) chloride / dichloromethane / 19 h / 20 °C / |Inert atmosphere 2.1: sodium methylate / methanol / 18 h / 20 °C / |Inert atmosphere 2.2: Dowex-H+ resin / 1 h / 20 °C / |Inert atmosphere View Scheme
参考文献
Barry, Conor S.; Cocinero, Emilio J.; Carcabal, Pierre; Gamblin, David P.; Stanca-Kaposta, E. Cristina; Remmert, Sarah M.; Fernandez-Alonso, Maria C.; Rudic, Svemir; Simons, John P.; Davis, Benjamin G.
Journal of the American Chemical Society, 2013 , vol. 135, # 45 p. 16895 - 16903
反应条件
iron(III) chloride in dichloromethane 1.) 5 min, 2.) r.t.;
参考文献
Chatterjee, Swapan K.; Nuhn, Peter
Chemical Communications, 1998 , # 16 p. 1729 - 1730
反应条件
1: 81 percent / HBr; AcOH / CH2Cl2 / 20 °C 2: 25 percent / AgOTf / CH2Cl2 / 0 °C View Scheme
参考文献
Nobrega, Chaxiraxi; Vazquez, Jesus T.
Tetrahedron Asymmetry, 2003 , vol. 14, # 18 p. 2793 - 2801
反应条件
boron trifluoride diethyl etherate in dichloromethane 2 h; Heating;
参考文献
Sofia, Michael J.; Kakarla, Ramesh; Kogan, Natan; Dulina, Richard; Hui; Hatzenbuhler, Nicole T.; Liu, Dashan; Chen, Anna; Wagler, Thomas
Bioorganic and Medicinal Chemistry Letters, 1997 , vol. 7, # 17 p. 2251 - 2254
