(E)-1-甲基-1,2二苯基乙烯合成路线 (共 175 条)
反应条件
15-crown-5; sodium hydride in tetrahydrofuran T=0 - 25°C; 16 h;
参考文献
Baker, Raymond; Sims, Russel J.
Synthesis, 1981 , # 2 p. 117
反应条件
Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran T=50°C; 3 h;
参考文献
Shi, Ji-cheng; Negishi, Ei-ichi
Journal of Organometallic Chemistry, 2003 , vol. 687, # 2 p. 518 - 524
反应条件
potassium carbonate in water T=80°C; Heck cross-coupling; 24 h; optical yield given as percent dediastereoselective reaction;
参考文献
Senra, Jaqueline D.; Malta, Luiz Fernando B.; Da Costa, Marcelo E. H. M.; Michel, Ricardo C.; Aguiar, Lucia C. S.; Simas, Alessandro B. C.; Antunes
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 14-15 p. 2411 - 2422
反应条件
NiCl2(PPh3)2 in tetrahydrofuran T=20°C; 12 h; Inert atmosphere;
参考文献
Yang, Zhaozhen; Chen, Xiaoyi; Kong, Wei; Xia, Siyuan; Zheng, Renwei; Luo, Fang; Zhu, Gangguo
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 13 p. 2175 - 2185
反应条件
aluminum oxide; potassium hydroxide; dibromo-difluoro-methane in tert-butyl alcohol T=5 - 20°C;
参考文献
Chan, Tze-Lock; Fong, Sun; Li, Yu; Man, Tim-On; Poon, Chi-Duen
Journal of the Chemical Society, Chemical Communications, 1994 , # 15 p. 1771 - 1772
反应条件
bis(.eta.(2)-ethylene)(2,4,-pentanedionato)rhodium; 1,4-di(diphenylphosphino)-butane in 1,4-dioxane; water T=100°C; 3 h; Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 123, # 40 p. 9918 - 9919
反应条件
palladium diacetate in acetonitrile T=25°C; 24 h; Yields of byproduct given;
参考文献
Matoba, Kazutaka; Motofusa, Shin-Ichi; Sik Cho, Chan; Ohe, Kouichi; Uemura, Sakae
Journal of Organometallic Chemistry, 1999 , vol. 574, # 1 p. 3 - 10
反应条件
AlCl3, aluminium chloride in tetrahydrofuran; 1,4-dioxane T=80°C; 8.16667 h; Inert atmosphereCooling with ice; optical yield given as percent destereoselective reaction;
参考文献
Peng, Zhi-Yong; Ma, Fang-Fang; Zhu, Lv-Feng; Xie, Xiao-Min; Zhang, Zhaoguo
Journal of Organic Chemistry, 2009 , vol. 74, # 17 p. 6855 - 6858
反应条件
sodium hydroxide in dichloromethane; para-xylene
反应条件
trifluoroacetic acid; methyl iodide in acetonitrile Heating a N2 satd. soln. of CH3I and boratirene on a steam bath.; Quenching with CF3CO2H, GC/MS.;
参考文献
Journal of the American Chemical Society, , vol. 113, # 6 p. 2155 - 2163