in water
byproducts: sulfide; finely divided (dust fineness) powder of S4N3Cl is moistened by a small amount of water, dissolved in cold aq. 2.5n NaOH and brought to boil in a flow of N2;; Product contains 50percent thiosulfate, 40percent sulfite, and 10percent sulfide;;
参考文献
Meuwsen, A.; Jakob, O.
Z. Anorg. Chem., 1950 , vol. 263, p. 200 - 212
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Gmelin Handbook: S: MVol.B3, 155, page 1858 - 1860
ammonia in tetrahydrofuran
gaseous ammonia is passed through a THF solution of (S4N3)Cl; NMR;
参考文献
Parkin, Ivan P.; Woollins, J. Derek; Belton, Peter S.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , p. 511 - 518
Zn in methanol
to methanolic suspension Zn dust is added under heavy shaking (in coldness); the leek green liquid turns dark red; (reaction should be stopped in time to avoid decompn. of S5N2 by Zn);; filtration; evapn. of filtrate;;
参考文献
Muthmann, W.; Clever, A.
Z. Anorg. Chem., 1897 , vol. 13, p. 200 - 208
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Gmelin Handbook: S: MVol.B3, 1, page 1131 - 1533
Zn in tetrahydrofuran
stirring at -5°C for 60 h under an atmosphere of dry N2; the solvent was pumped off at -15°C to dryness, reaction products were allowed to warm up to room temp., pumping for 6 h to sublime the product, repeated vac. sublimation;
参考文献
Small, Ronald W. H.; Banister, Arthur J.; Hauptman, Zdenek V.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981 , p. 2188 - 2191
