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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
3-溴噻吩
合成路线
（共 355 条）
872-31-1
3-溴噻吩
+
112-29-8
癸基溴
→
反应条件
65016-55-9
3-癸基噻吩
反应条件
1: 1-bromo-decane With magnesium in diethyl ether Reflux; 2: thien-3-yl bromide With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether T=0°C; RefluxInert atmosphere;
参考文献
Wang, Bao; Tsang, Sai-Wing; Zhang, Weifeng; Tao, Ye; Wong, Man Shing
Chemical Communications, 2011 , vol. 47, # 33 p. 9471 - 9473
872-31-1
3-溴噻吩
→
反应条件
3172-56-3
3,3'-双噻吩
+
65016-55-9
3-癸基噻吩
反应条件
1: 1-bromo-decane With magnesium; [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in 2-methyl tetrahydrofuran T=20°C; 2.5 h; 2: thien-3-yl bromide in 2-methyl tetrahydrofuran T=20°C; Kumada Coupling Reaction; Product distribution / selectivity;
参考文献
US2006/155134 A1, ;
Page/Page column 3 ;
872-31-1
3-溴噻吩
+
112-29-8
癸基溴
→
反应条件
3172-56-3
3,3'-双噻吩
+
740804-46-0
+
65016-55-9
3-癸基噻吩
反应条件
1: thien-3-yl bromide; 1-bromo-decane With magnesium; [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran T=20°C; 48 h; 2: thien-3-yl bromide in 2-methyl tetrahydrofuran T=20°C; Kumada Coupling Reaction; Product distribution / selectivity;
参考文献
US2006/155134 A1, ;
Page/Page column 5 ;
872-31-1
3-溴噻吩
+
108-95-2
苯酚
→
反应条件
63285-84-7
3-苯氧基噻吩
反应条件
Copper(I)chloride in pyridine; mineral oil
参考文献
US2002/95041 A1, ;
872-31-1
3-溴噻吩
→
反应条件
60404-24-2
3-溴-2-碘噻吩
反应条件
N-iodo-succinimide in chloroform; acetic acid T=20°C; 48 h;
参考文献
Heinrich, Annika C. J.; Thiedemann, Birk; Gates, Paul J.; Staubitz, Anne
Organic Letters, 2013 , vol. 15, # 18 p. 4666 - 4669
872-31-1
3-溴噻吩
+
63468-90-6
→
反应条件
6453-99-2
苯基-3-噻吩基-甲酮
反应条件
1: With 1,1'-bis-(diphenylphosphino)ferrocene; 1,10-phenanthroline; Pd(F6-acac)2; cyclohexylamine; copper(I) bromide in quinoline T=100°C; 10 h; Inert atmosphereMolecular sieve; 2: With hydrogenchloride in tetrahydrofuran; quinoline; water T=80°C; 1 h; Inert atmosphere;
参考文献
Collet, Florence; Song, Bingrui; Rudolphi, Felix; Goossen, Lukas J.
European Journal of Organic Chemistry, 2011 , # 32 p. 6486 - 6501
872-31-1
3-溴噻吩
+
100-47-0
苯甲腈
→
反应条件
6453-99-2
苯基-3-噻吩基-甲酮
反应条件
1: thien-3-yl bromide With n-butyllithium in tetrahydrofuran; diethyl ether; hexane T=-78 - -70°C; 0.25 h; 2: benzonitrile in tetrahydrofuran; diethyl ether; hexane T=-78 - -10°C; 3 h; 3: With hydrogenchloride; water 2 h; Heating / reflux;
参考文献
Carson, John R.; Lee, Jung S.
Patent: US2005/171099 A1, 2005 ;
Location in patent: Page/Page column 12 ;
872-31-1
3-溴噻吩
+
201230-82-2
+
98-80-6
苯硼酸
→
反应条件
6453-99-2
苯基-3-噻吩基-甲酮
反应条件
N,N,N',N,-tetramethylethylenediamine; α-n-hexadecene; palladium diacetate; di-(1-adamantyl)-n-butylphosphine in toluene T=100°C; Suzuki reaction; P=3750.38 Torr; 24 h; AutoclaveInert atmosphere;
参考文献
Neumann, Helfried; Brennfuehrer, Anne; Beller, Matthias
Chemistry - A European Journal, 2008 , vol. 14, # 12 p. 3645 - 3652
872-31-1
3-溴噻吩
+
5908-41-8
→
反应条件
6453-99-2
苯基-3-噻吩基-甲酮
反应条件
potassium phosphate; PdCl(NH2C6H4C6H4)(C6H4(CH3)4O3PC6H5); water in 2-methyl tetrahydrofuran T=60°C; 24 h; Inert atmosphere;
参考文献
Schmink, Jason R.; Krska, Shane W.
Journal of the American Chemical Society, 2011 , vol. 133, # 49 p. 19574 - 19577
872-31-1
3-溴噻吩
+
98-88-4
苯甲酰氯
→
反应条件
6453-99-2
苯基-3-噻吩基-甲酮
反应条件
manganese; ethylene dibromide in tetrahydrofuran 1.) 0 deg C to rt, 1 h; 2.) 0 deg C, 20 min; 3.) rt, 30 min;
参考文献
Kim, Seung-Hoi; Hanson, Mark V.; Rieke, Reuben D.
Tetrahedron Letters, 1996 , vol. 37, # 13 p. 2197 - 2200
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