2,4,6-三甲基苯胺合成路线 （共 254 条）
反应条件
potassium permanganate; copper(II) sulfate in dichloromethane
24 h; Heating;
参考文献
Noureldin, Nazih A.; Bellegarde, Jody W.
Synthesis, 1999 , # 6 p. 939 - 942
反应条件
di-tert-butyl peroxide; {[Cl2NNF6]Cu}2(benzene) in benzene
T=60°C; 18 h;
参考文献
Georgetown University
Patent: US2011/213146 A1, 2011 ;
Location in patent: Page/Page column 3; 27 ;
反应条件
1,2,4,5-TeCB; di-tert-butyl peroxide; (-)-2,2′-isopropylidenebis[(4S)-4-phenyl-2-oxazoline]; [Cu(I)(CH3CN)4]PF6
T=80°C; 18 h; Product distribution / selectivity;
参考文献
Georgetown University
Patent: US2011/213146 A1, 2011 ;
Location in patent: Page/Page column 26 ;
反应条件
potassium dichromate; acetic acid in methanol; water
4 h; Ambient temperature;
参考文献
Goldstein, Stephen L.; McNelis, Edward
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1613 - 1620
参考文献
Chapman; Saunders
Journal of the Chemical Society, 1941 , p. 496,499
参考文献
Horner; Kirmse
Justus Liebigs Annalen der Chemie, 1955 , vol. 597, p. 48,53
反应条件
1: 2,4,6-trimethylbenzenamine With 15-crown-5; sodium hydride in benzene
T=40 - 50°C; 0.25 h;
2: chloroform in benzene
T=40°C; 1 h;
参考文献
Bardsley, Kathryn; Hagigeorgiou, Michael; Lengyel, Istvan; Cesare, Victor
Synthetic Communications, 2013 , vol. 43, # 12 p. 1727 - 1733
反应条件
1.1: 12 h / 200 °C / Autoclave
2.1: trichlorophosphate / dichloromethane / 0.42 h / -60 °C
2.2: -60 - 20 °C
View Scheme
参考文献
BASF SE
Patent: US2012/108819 A1, 2012 ;
Title/Abstract Full Text Show Details
BASF SE; BASF (CHINA) COMPANY LIMITED; HASHMI, A., Stephen K.; LOTHSCHUeTZ, Christian
Patent: WO2012/56419 A1, 2012 ;
反应条件
tert.-butylnitrite; methanesulfonic acid; palladium diacetate in methanol
T=25°C; Heck Reaction; 48 h;
参考文献
Oger, Nicolas; Le Callonnec, Francois; Jacquemin, Denis; Fouquet, Eric; Le Grognec, Erwan; Felpin, Francois-Xavier
Advanced Synthesis and Catalysis, 2014 , vol. 356, # 5 p. 1065 - 1071
参考文献
Universal Oil Prod. Co.
Patent: US2733249 , 1956 ;
