acetic acid bei der Chlorierung;

chlorine; acetic acid

1: (oxidation) 2: Cl2, AcOH View Scheme

暂无反应条件数据

1: 91 percent / NaHCO3 / dimethylformamide / 12 h / 60 °C 2: 52 percent / diphenyl ether / 1 h / 225 - 230 °C View Scheme

sodium hydrogencarbonate in N,N-dimethyl-formamide T=60°C; 12 h;

1: 91 percent / NaHCO3 / dimethylformamide / 12 h / 60 °C 2: 52 percent / diphenyl ether / 1 h / 225 - 230 °C 3: 72 percent / 85percent m-chloroperoxybenzoic acid / CH2Cl2 / 20 h / Ambient temperature 4: 41 percent / Jones reagent / acetone / 2 h 5: 95 percent / conc. H2SO4 / 1,2-dichloro-ethane / 1.5 h / Heating 6: dimethylformamide / 9 h / 160 - 163 °C 7: Fe powder / ethanol; acetic acid / 0.5 h / 80 - 85 °C 8: 47 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / benzene / 16 h / Ambient temperature View Scheme

1: 91 percent / NaHCO3 / dimethylformamide / 12 h / 60 °C 2: 52 percent / diphenyl ether / 1 h / 225 - 230 °C 3: 72 percent / 85percent m-chloroperoxybenzoic acid / CH2Cl2 / 20 h / Ambient temperature 4: 41 percent / Jones reagent / acetone / 2 h 5: 95 percent / conc. H2SO4 / 1,2-dichloro-ethane / 1.5 h / Heating 6: dimethylformamide / 9 h / 160 - 163 °C 7: Fe powder / ethanol; acetic acid / 0.5 h / 80 - 85 °C 8: 68 percent / Cu2Br2, Na2CO3 / various solvent(s) / 5.5 h / 170 °C 9: 81 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / benzene / 6 h / Heating View Scheme