in chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR;

1: CH3COCl 2: O2 View Scheme

暂无反应条件数据

in ethanol; chloroform byproducts: NaCH3COO; in a dry box flushed with N2; mixing an alc./CHCl3 soln. of dithiocarbamate with Sn-compd. in alc., stirring for ca 2 h; elem. anal.;

in N,N-dimethyl acetamide Electrolysis; supporting electrolite LiClO4; filtration, washing with methanol then ether;

water in tetrahydrofuran; diethyl ether; ethanol to THF soln. of Sn compd. added BH3 (N2, room temp.),refluxed (1 h), added H2O,stirred (30 min),extd. (Et2O), dried (MgSO4),evapd. in vac.,heated with pentane,filtered PhB(OH)2,filtrate evapd.,added Et2O,EtOH soln. of HOCH2CH2NH2 added,refluxed (30 min); filtered hot, complex pptd. by cooling, filtered; PhB(OH)2 recrystd. from H2O; compds. identified by m. p., IR, NMR;