1,8-diazabicyclo{5.4.0}undec-7-ene in cellosolve=2-ethoxyethanol a mixt. of the Cu salt, phthalonitrile, and the base (molar ratio 3:10:10) was refluxed in ethyl-cellosolve for 6 h;; the ppt. was filtered off, washed with water and ethanol, and purified by extrn. with CHCl3; IR, UV, XRD, and elem.anal.;;
sodium methylate in methanol pyrophoric Ni under water layer added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30percent soln of CH3ONa in methanol; flask maintained at 25°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97percent; elem. anal.;
参考文献
Kharisov; Coronado, C.E. Cantu; Cerda, K.P. Coronado; Mendez, U. Ortiz; Guzman, J.A. Jacobo; Patlan, L.A. Ramirez
Inorganic Chemistry Communications, 2004 , vol. 7, # 12 p. 1269 - 1272
in methanol reflux in methanol soln. ca. at 65°C for 24 h; vac. sublimation;
参考文献
Kopylovich, Maximilian N.; Kukushkin, Vadim Yu.; Haukka, Matti; Luzyanin, Konstantin V.; Pombeiro, Armando J. L.
Journal of the American Chemical Society, 2004 , vol. 126, # 46 p. 15040 - 15041
