N-methyl-pyrrolidine; hydrogen; tetracarbonylbis(μ-chloro)dirhodium(I) in benzene
T=80°C; P=44130.5 Torr; 0.333333 h; var. conc. of 1-hexene, other amine (aminated polystyrene); Product distribution;
参考文献
Mizoroki; Kioka; Suzuki; Sakatani; Okumura; Maruya
Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 2 p. 577 - 578
H2; CO in benzene-d6
byproducts: 2-hexenes; High Pressure; React. in a high-pressure react. vessel with CO/H2 (1200 psi), stirring (18 h), recharging with CO/H2 (900 psi), heating (1.75 h, 67°C).; Monitored by (1)H-NMR and GC.;
参考文献
Thaler, Eric G.; Folting, Kirsten; Caulton, Kenneth G.
Journal of the American Chemical Society, 1990 , vol. 112, # 7 p. 2664 - 2672