3,4-环氧-1-丁烯合成路线 (共 241 条)
反应条件
1: Butadiene monooxide With 3,3-dimethyldioxirane in acetone T=-15°C; 2.5 h; 2: L-2'-deoxyguanosine in acetic acid T=60°C; 22 h; 3: With hydrogenchloride T=80°C; 2.5 h;
参考文献
Oe, Tomoyuki; Kambouris, Sara J.; Walker, Vernon E.; Meng, Quanxin; Recio, Leslie; Wherli, Suzanne; Chaudhary, Ajai K.; Blair, Ian A.
Chemical Research in Toxicology, 1999 , vol. 12, # 3 p. 247 - 257
反应条件
NHep4(1+)*I(1-); tributyl tin (1+); iodide in para-xylene T=109 - 117°C; 0.75 h;
参考文献
Eastman Chemical Company
Patent: US6342614 B1, 2002 ;
Location in patent: Example 327 ;
反应条件
indium in tetrahydrofuran Grignard type reaction; 1 h;
参考文献
Oh, Byung Kyu; Cha, Joo Hwan; Cho, Yong Seo; Choi, Kyung Il; Koh, Hun Yeong; Chang, Moon Ho; Pae, Ae Nim
Tetrahedron Letters, 2003 , vol. 44, # 14 p. 2911 - 2913
反应条件
1: T=60°C; Allylboration; 24 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water T=20°C; Oxidation; 4 h; Further stages.;
参考文献
Zaidlewicz, Marek; Krzeminski, Marek P.
Organic Letters, 2000 , vol. 2, # 24 p. 3897 - 3899
参考文献
Freedman; Becker
Journal of Organic Chemistry, 1951 , vol. 16, p. 1701,1708
参考文献
Freedman; Becker
Journal of Organic Chemistry, 1951 , vol. 16, p. 1701,1708
反应条件
hydrogen; silica gel; palladium T=-0.15°C; P=150.012 Torr; also ethyloxirane; also with duterium; also over Pt-SiO2; var. temp. and time; Product distributionMechanism;
参考文献
Bartok, Mihaly; Fasi, Andras; Notheisz, Ferenc
Journal of Catalysis, 1998 , vol. 175, # 1 p. 40 - 47
反应条件
hydrogen in ethanol T=30°C; P=4500.45 Torr; Reagent/catalystSolventTemperature;
参考文献
Kahsar, Karl R.; Schwartz, Daniel K.; Medlin, J. Will
Applied Catalysis A: General, 2012 , vol. 445-446, p. 102 - 106
反应条件
hydrogen; lt;Rh(NBD)(PPh3)2gt;lt;ClO4gt; T=30°C; P=760 Torr; 8 h; catalytic hydrogenation of the title compound in the presence of various catalysts (cationic rhodium complexes); influence of the type of catalyst's ligand, reaction time and pressure on the activity of catalysts; Product distributionMechanism;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 855 - 860
反应条件
hydrogen; Ag-Pt/SiO2 KineticsProduct distribution; Further Variations:Catalystseffect of Ag addition;
参考文献
Schaal, Melanie T.; Pickerell, Anna C.; Williams, Christopher T.; Monnier, John R.
Journal of Catalysis, 2008 , vol. 254, # 1 p. 131 - 143