2,5-二氢-1-甲基-1H-磷杂环戊二烯 1-氧化物合成路线 （共 7 条）
反应条件
(i) nBuLi, THF, (ii) /BRN= 1900390/, (iii) ion-exchange resin <H+ form>; Multistep reaction;
参考文献
Quin,L.D.; Borleske,S.G.
Tetrahedron Letters, 1972 , p. 299 - 302
反应条件
T=0 - 20°C; 4.16667 h;
参考文献
Richter, Frank U.
Chemistry - A European Journal, 2009 , vol. 15, # 21 p. 5200 - 5202
参考文献
Richter, Frank U.
Chemistry - A European Journal, 2009 , vol. 15, # 21 p. 5200 - 5202
反应条件
1: H2 / PtO2 / ethanol
2: PhSiH3
3: benzene
View Scheme
参考文献
Marsi,K.L.
Journal of the American Chemical Society, 1969 , vol. 91, p. 4724 - 4729
反应条件
bromine in chloroform
参考文献
Quin,L.D.; Peters,J.A.
Tetrahedron Letters, 1964 , # 48 p. 3689 - 3693
反应条件
hydrogen; platinum(IV) oxide in ethanol
参考文献
Marsi,K.L.
Journal of the American Chemical Society, 1969 , vol. 91, p. 4724 - 4729
反应条件
1: 81 percent / m-chloroperbenzoic acid / CH2Cl2 / 24 h / Heating
2: 67 percent / phenylsilane / 1 h / 80 °C
3: benzene
View Scheme
参考文献
Quin, Louis D.; Symmes, Courtland; Middlemas, Eric D.; Lawson, H. Franklin
Journal of Organic Chemistry, 1980 , vol. 45, # 23 p. 4688 - 4694
