1: triphenylborane With diethylzinc in hexane; toluene T=20 - 80°C; 2: cyclohexenon With monodentate phosphoramidite ligand; copper(II) bis(trifluoromethanesulfonate) in hexane; toluene T=0°C; 16 h; Title compound not separated from byproducts;
参考文献
Pena, Diego; Lopez, Fernando; Harutyunyan, Syuzanna R.; Minnaard, Adriaan J.; Feringa, Ben L.
Chemical Communications, 2004 , # 16 p. 1836 - 1837
1: diphenyl-difluoro-silane With tris(dimethylamino)-sulphonium difluorotrimethylsilicate in dichloromethane 0.0833333 h; Inert atmosphere; 2: cyclohexenon With C41H42BrCuN2 in dichloromethane T=40°C; 20 h; Inert atmosphere; 3: With hydrogenchloride; water in dichloromethane optical yield given as percent eeenantioselective reaction;
参考文献
Lee, Kang-Sang; Hoveyda, Amir H.
Journal of Organic Chemistry, 2009 , vol. 74, # 12 p. 4455 - 4462
bis(.eta.(2)-ethylene)(2,4,-pentanedionato)rhodium; Sp-(C16H15)2C3H5N2(1+)*BF4(1-) in tetrahydrofuran; water T=60°C; 3 h; Product distribution; Further Variations:ReagentsTemperaturesSolventsreaction times;
参考文献
Ma, Yudao; Song, Chun; Ma, Changqing; Sun, Zhijun; Chai, Qiang; Andrus, Merritt B.
Angewandte Chemie - International Edition, 2003 , vol. 42, # 47 p. 5871 - 5874
(1S,2S,4S,5S)-2,5-(Ph2P)2-norbornane; potassium hydroxide; [Rh(C2H4)2Cl]2 in 1,4-dioxane; water T=60°C; 4 h; Product distribution; Further Variations:TemperaturesSolvents;
参考文献
Iuliano, Anna; Facchetti, Sarah; Funaioli, Tiziana
Chemical Communications, 2009 , # 4 p. 457 - 459
