5-正辛基-2,2'-并噻吩合成路线 （共 5 条）
反应条件
1: 2-(thien-2-yl)thiophene With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 20°C;
2: 1-bromo-octane in tetrahydrofuran; hexane
10 h;
参考文献
NATIONAL CENTRAL UNIVERSITY
Patent: US2009/209761 A1, 2009 ;
Location in patent: Page/Page column 9 ;
反应条件
potassium hydroxide; hydrazine hydrate in various solvent(s)
参考文献
Kossmehl, Gerhard; Labahn, Bettina
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 2 p. 286 - 294
反应条件
1: SOCl2 / 2 h / Heating
2: 66 percent / SnCl4 / 1,2-dichloro-ethane / Ambient temperature
3: 79 percent / 99percent NH2NH2*H2O, KOH / various solvent(s)
View Scheme
参考文献
Kossmehl, Gerhard; Labahn, Bettina
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 2 p. 286 - 294
反应条件
1: 66 percent / SnCl4 / 1,2-dichloro-ethane / Ambient temperature
2: 79 percent / 99percent NH2NH2*H2O, KOH / various solvent(s)
View Scheme
参考文献
Kossmehl, Gerhard; Labahn, Bettina
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 2 p. 286 - 294
反应条件
1: TiCl4 / CH2Cl2 / Ambient temperature
2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / Heating
3: KOH / bis-(2-hydroxy-ethyl) ether / Heating
View Scheme
参考文献
Byron, David; Matharu, Avtar; Wilson, Robert; Wright, Gavin
Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1995 , vol. 265, p. 61 - 76
