1,2,3,4-四氢咔唑合成路线 （共 202 条）
反应条件
1,4-diaza-bicyclo[2.2.2]octane; palladium diacetate in N,N-dimethyl-formamide T=105°C; 3 h;
参考文献
Chen; Lieberman; Larsen; Verhoeven; Reider
Journal of Organic Chemistry, 1997 , vol. 62, # 9 p. 2676 - 2677
反应条件
[(IPr)Pd(acac)Cl]; potassium tert-butylate; magnesium sulfate in toluene T=100°C; 12 h; Inert atmosphere;
参考文献
Jin, Zhong; Guo, Su-Xian; Qiu, Ling-Ling; Wu, Gui-Ping; Fang, Jian-Xin
Applied Organometallic Chemistry, 2011 , vol. 25, # 7 p. 502 - 507
反应条件
ammonium formate; palladium on activated charcoal in methanol 2 h; Heating;
参考文献
Synthesis, , # 10 p. 778 - 781
反应条件
[{(η5-C5Me5)IrCl}2(μ-Cl)2]; methanesulfonic acid T=170°C; 48 h; Inert atmosphere;
参考文献
Tursky, Matyas; Lorentz-Petersen, Linda L. R.; Olsen, Lasse B.; Madsen, Robert
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 24 p. 5576 - 5582
反应条件
1: 79 percent / xantphos; cesium carbonate / Pd2(dba)3 / dioxane / 24 h / 115 °C / 9 2: KOH / H2O; ethanol / 2 h / Heating View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 3 p. 403 - 406
反应条件
1.1: 78 percent / xantphos; cesium carbonate / Pd2(dba)3 / dioxane / 24 h / 80 °C 2.1: sodium hydride / dimethylformamide / 3 h / 0 °C 2.2: 87 percent / dimethylformamide / 20 °C 3.1: 79 percent / xantphos; cesium carbonate / Pd2(dba)3 / dioxane / 24 h / 115 °C / 9 4.1: KOH / H2O; ethanol / 2 h / Heating View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 3 p. 403 - 406
反应条件
1.1: sodium hydride / dimethylformamide / 3 h / 0 °C 1.2: 87 percent / dimethylformamide / 20 °C 2.1: 79 percent / xantphos; cesium carbonate / Pd2(dba)3 / dioxane / 24 h / 115 °C / 9 3.1: KOH / H2O; ethanol / 2 h / Heating View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 3 p. 403 - 406
反应条件
1.1: 78 percent / xantphos; cesium carbonate / Pd2(dba)3 / dioxane / 24 h / 80 °C 2.1: sodium hydride / dimethylformamide / 3 h / 0 °C 2.2: 87 percent / dimethylformamide / 20 °C 3.1: 79 percent / xantphos; cesium carbonate / Pd2(dba)3 / dioxane / 24 h / 115 °C / 9 4.1: KOH / H2O; ethanol / 2 h / Heating View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 3 p. 403 - 406
反应条件
dirhodium(II) tetraoctanoate in 1,2-dichloro-ethane T=70°C; 16 h; Inert atmosphereMolecular sieve;
参考文献
Sun, Ke; Liu, Sheng; Bec, Patryk M.; Driver, Tom G.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 7 p. 1702 - 1706
反应条件
zinc(II) chloride in acetic acid T=120°C; Fischer Indole Synthesis; 3 h;
参考文献
Douglas, Nicholas; Neef, Charles J.; Rogers, Robert A.; Stanley, Jake A.; Armitage, Jacob; Martin, Ben; Hudnall, Todd W.; Brittain, William J.
Journal of Physical Organic Chemistry, 2013 , vol. 26, # 8 p. 688 - 695
