16,17-alpha环氧孕烯醇酮合成路线 （共 20 条）
反应条件
1: acetic acid; HBr 2: palladium/charcoal; methanol; ammonium acetate / Hydrogenation 3: water 4: toluene-4-sulfonic acid 5: aluminium isopropylate; cyclohexanone; xylene 6: aqueous methanol.KOH View Scheme
参考文献
Ringold et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 820,823
反应条件
1: acetic acid; HBr 2: palladium/charcoal; methanol; ammonium acetate / Hydrogenation 3: water 4: toluene-4-sulfonic acid 5: aluminium isopropylate; cyclohexanone; xylene View Scheme
参考文献
Ringold et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 820,823
反应条件
ethanol; palladium Hydrogenation;
参考文献
Ercoli; de Ruggieri
Gazzetta Chimica Italiana, 1954 , vol. 84, p. 479,487
反应条件
cyclohexanone; aluminum isopropoxide; toluene
参考文献
Huang-Minlon et al.
Huaxue Xuebao, 1959 , vol. 25, p. 295,298
Chem.Abstr., 1960 , p. 17470
反应条件
1: acetic acid; HBr 2: palladium/charcoal; methanol; ammonium acetate / Hydrogenation 3: water 4: toluene-4-sulfonic acid 5: aluminium isopropylate; cyclohexanone; xylene View Scheme
参考文献
Ringold et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 820,823
反应条件
1: acetic acid; HBr 2: palladium/charcoal; methanol; ammonium acetate / Hydrogenation 3: water 4: toluene-4-sulfonic acid 5: aluminium isopropylate; cyclohexanone; xylene View Scheme
参考文献
Ringold et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 820,823
反应条件
3-hydroxy-pyridine; carbon monoxide; dicobalt octacarbonyl in tetrahydrofuran; ethanol T=75°C; P=76000 Torr; 72 h;
参考文献
Balazs, Attila; Benedek, Csilla; Szalontai, Gabor; Toroes, Szilard
Steroids, 2004 , vol. 69, # 4 p. 271 - 277
反应条件
hydrogen bromide in 1,4-dioxane T=25°C; 6 h;
参考文献
Cabeza, Marisa; Bratoeff, Eugene; Flores, Eugenio; Ramirez, Elena; Calleros, Jorge; Montes, Diana; Quiroz, Alexandra; Heuze, Ivonne
Chemical and pharmaceutical bulletin, 2002 , vol. 50, # 11 p. 1447 - 1452
参考文献
Romo; Romo de Vivar
Journal of Organic Chemistry, 1956 , vol. 21, p. 902,906
Full Text Show Details
Patel et al.
Journal of the Chemical Society, 1957 , p. 665,668
Full Text Show Details
Ringold et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 820,823
反应条件
1: chromium (VI)-oxide; concentrated sulfuric acid 2: rhizopus-nigricans-cultures View Scheme
参考文献
Huang-Minlon et al.
Huaxue Xuebao, 1959 , vol. 25, p. 295,298
Chem.Abstr., 1960 , p. 17470
