in diethylene glycol dimethyl ether
byproducts: H2; further intermediate: KSiH3; under N2, dispersion of potassium reacts with SiH4 at 100°C, soln. of PhSO3H added dropwise at -40°C; volatiles removed at room temp. in vacuo, SiH4 removed; GC;
in diethylene glycol dimethyl ether
byproducts: H2; further intermediate: NaSiH3; under N2, dispersion of sodium reacts with SiH4 at 100°C, soln. of PhSO3H added dropwise at -40°C; volatiles removed at room temp. in vacuo, SiH4 removed; GC;
in toluene
1:2; azeotropic dehydration; boiling for 2-4 h; removal of solvent;
参考文献
Blunden, S. J.; Chapman, A. H.; Crowe, A. J.; Smith, P. J.
Intern. Pest Control., 1978 , vol. 20, p. 12
Full Text Show Details
Gmelin Handbook: Sn: Org.Comp.12, 1.4.1.1.1.5.12, page 206 - 211
