反应条件
1: 240 g / Zn / benzene / Heating 2: 1.) p-toluenesulfonic acid, 2.) 10percent NaOH / 1.) toluene, reflux, 3 h, 2.) reflux, 2 h 3: 37 percent / 1.) N-bromosuccinimide, 2.) NH3 / 1.) CCl4, reflux, 48 h, 2.) THF, 3 h 4: 16 percent / NH3 / tetrahydrofuran / 3 h 5: 65 percent / 1 M NH4OH / 1 h / 70 °C 6: 59 percent / H2, Raney nickel W-5 / ethanol / 16 h / 3040 Torr / Ambient temperature View Scheme
参考文献
Allan; Tran
Australian Journal of Chemistry, 1981 , vol. 34, # 12 p. 2641 - 2645
