4-(2-噻吩基)-3-烯-2-丁酮合成路线 （共 8 条）
反应条件
Jone's reagent in diethyl ether
T=0 - 20°C; Inert atmosphere;
参考文献
Zhu, Liping; Yu, Hongmei; Xu, Zhaoqing; Jiang, Xianxing; Lin, Li; Wang, Rui
Organic Letters, 2014 , vol. 16, # 6 p. 1562 - 1565
反应条件
in tetrahydrofuran
T=65°C; 4 h;
参考文献
Katritzky, Alan R.; Le, Khanh N. B.; Khelashvili, Levan; Mohapatra, Prabhu P.
Journal of Organic Chemistry, 2006 , vol. 71, # 26 p. 9861 - 9864
反应条件
1: zinc / tetrahydrofuran / 0 °C / |Inert atmosphere
2: Jone's reagent / diethyl ether / 0 - 20 °C / |Inert atmosphere
View Scheme
参考文献
Zhu, Liping; Yu, Hongmei; Xu, Zhaoqing; Jiang, Xianxing; Lin, Li; Wang, Rui
Organic Letters, 2014 , vol. 16, # 6 p. 1562 - 1565
反应条件
aluminium trichloride in carbon disulfide
3 h; Ambient temperature;
参考文献
El-Khagawa, Ahmed M.; El-Zohry, Maher F.; Ismail, Mohamed T.
Phosphorus and Sulfur and the Related Elements, 1987 , vol. 33, p. 25 - 32
反应条件
iron(III) chloride in carbon disulfide
3 h; Ambient temperature; Further byproducts given;
参考文献
El-Khagawa, Ahmed M.; El-Zohry, Maher F.; Ismail, Mohamed T.
Phosphorus and Sulfur and the Related Elements, 1987 , vol. 33, p. 25 - 32
反应条件
tetrachlorosilane; benzene
Behandeln des Reaktionsgemisches mit Thiophen und Zinn(IV)-chlorid;
参考文献
Jur'ew et al.
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 3194,3197; engl. Ausg. S. 3559, 3562
反应条件
iron(III) chloride in carbon disulfide
3 h; Ambient temperatureother catalyst; Product distribution;
参考文献
El-Khagawa, Ahmed M.; El-Zohry, Maher F.; Ismail, Mohamed T.
Phosphorus and Sulfur and the Related Elements, 1987 , vol. 33, p. 25 - 32
反应条件
1: hydroxylamine hydrochloride; sodium acetate / water; ethanol / 20 °C
2: triethylamine / dichloromethane / 0 °C
3: copper(I) bromide / toluene / 120 °C / |Inert atmosphere
View Scheme
参考文献
Du, Wei; Zhao, Mi-Na; Ren, Zhi-Hui; Wang, Yao-Yu; Guan, Zheng-Hui
Chemical Communications, 2014 , vol. 50, # 56 p. 7437 - 7439
