1: trimethylsilylacetylene With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: With zinc dibromide in tetrahydrofuran; hexane T=0°C; 3: 4-pyridinecarbonitrile With n-tridecane; [NiCl2(PMe3)2] in tetrahydrofuran T=65°C; 20 h; Further stages.;
参考文献
Penney, Jonathan M.; Miller, Joseph A.
Tetrahedron Letters, 2004 , vol. 45, # 25 p. 4989 - 4992
dipotassium peroxodisulfate; sulfuric acid; copper diacetate; silver nitrate in water T=57°C; 3 h; without cupric acetate, various temperatures and acidities, (NH4)2S2O8 for K2S2O8; Product distributionRate constantMechanism;
参考文献
Journal of Organic Chemistry, , vol. 45, # 23 p. 4752 - 4757
