HNO3 or CH3CO2H in not given heating PCl5 with NaNH2 under inflammation; sublimate contains NH4Cl, NaCl and an insol. P-compound; react. of sublimate with HNO3 or CH3CO2H;; composition PNO2 or PNO2H;;
参考文献
Gmelin Handbook: P: MVol.C, 144, page 331 - 333
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反应条件
in neat (no solvent) reaction on slightly warming under intensive appearance of flames;; formation of a sublimate of NH4Cl, NaCl and an insol. P-compound, which can not be isolated without decompn.;;
