in neat (no solvent)
react. of PCl5 with SO3 vapor; formation of SO2Cl2 and adduct SO2ClO-PCl3-OClO2S; decompn. of SO2Cl2 forming SO2 and Cl2, decompn. of adduct forming a small amount of S2O5Cl2;;
参考文献
Oddo, G.; Sconza, A.
Gazzetta Chimica Italiana, 1927 , vol. 57, p. 83 - 103
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Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in neat (no solvent)
byproducts: SO2Cl2; heating on a water bath with a reflux condenser; formation of SO2, Cl2, POCl3, small amount of SOCl2 and S2O5Cl2 and traces of SO2Cl2;;
参考文献
Michaelis, A.
Jena. Z. Med. Naturwiss., 1871 , vol. 6, p. 292 - 295
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Gmelin Handbook: P: MVol.C, 195, page 447 - 449
