in neat (no solvent) mixing powdered KClO3 with PCl5; liquefaction of the mass under evolution of heat; at first formation of a gas with detonation, then evolution of Cl2; formation of pure KCl as residue;;
参考文献
Gmelin Handbook: P: MVol.C, 194, page 445 - 447
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Spring, W.
Bull. Cl. Sci. Acad. Roy. Belgique (2), 1875 , vol. 39, p. 882 - 911
Geuther, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 380 - 390
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Geuther, A.
J. prakt. Chem. (2), 1874 , vol. 8, p. 359 - 372
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Gmelin Handbook: P: MVol.C, 193, page 443 - 445
Thorpe, T. E.; Tutton, A. E.
Journal of the Chemical Society, 1891 , vol. 59, p. 1019 - 1029
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Gmelin Handbook: P: MVol.C, 200, page 458 - 460
in not given react. of H4P2O7 with an excess of PCl5 at water bath temp.;;
参考文献
Geuther, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 380 - 390
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Geuther, A.
J. prakt. Chem. (2), 1874 , vol. 8, p. 359 - 372
Full Text Show Details
Gmelin Handbook: P: MVol.C, 193, page 443 - 445