1,2,3,4,5,6,7,8-八硫杂环辛烷合成路线 （共 272 条）
反应条件
in neat (no solvent) heating under > 200 hPa SO2;
参考文献
Inorganic Chemistry, , vol. 36, # 24 p. 5570 - 5573
反应条件
in neat (no solvent) byproducts: H2O; redn. of SO2 by H2 below 500°C, investigation of equilibrium constants;; practically no SO and S obtained;;
参考文献
Journal of Chemical Physics, , vol. 3, p. 336 - 336
反应条件
in carbon disulfide; water byproducts: S(x); CS2 soln. of S2Cl2 shaked with aq. KI soln. for 5 min, standing at 20°C for ca 15 min, org. phase sepd., washed with Na2S2O3 soln. (elimination of I2) various S contg. CS2 soln. sepd., dried with CaCl2, filtered,; concd. in vac. at 20°C to small volume, n-pentane added, oily by-products sepd., decanted soln. cooled to -78°C, S6 crystd. together with S8, purifn. repeated recrystn. from CS2 at -78°C give S6, all products sepd.;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 463, p. 27 - 31
反应条件
in gas detected by IR spectra;
参考文献
Inorganic Chemistry, , vol. 20, p. 1325 - 1326
反应条件
in carbon disulfide byproducts: HBr; dropping H2S2 into BBr3; very good yield;
参考文献
Angewandte Chemie, , vol. 76, p. 687
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 345, p. 87 - 92
B: B-Verb.3, 2.9.2, page 38 - 40
反应条件
in neat (no solvent) byproducts: CO2; equilibrium below 800°C, polymn. of S2 to S6 and S8;;
参考文献
Zhurnal khim. Promyshlennosti (russ.), , vol. 2, p. 474 - 478
反应条件
in carbon disulfide inert atmosphere; other solvent: CH2Cl2;
参考文献
Chemische Berichte, , vol. 128, # 6 p. 561 - 564
反应条件
in neat (no solvent) byproducts: sulfur; decompn. at 78°C to polymeric S and S8;;
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 41, # 8 p. 958 - 970
反应条件
in tetrachloromethane Irradiation (UV/VIS); high pressure Hg-lamp (125 W, 250-350 nm) or exposing to sunlight for 1- 2 months; detd. by UV spectroscopy;
参考文献
Inorganica Chimica Acta, , vol. 232, p. 27 - 34
反应条件
in toluene N2 atmosphere; addn. of soln. of (Me2BS)2 to soln. of BN(BBr2)2 (-10°C, stirring), warming to room temp., stirring (room temp., 48 h); filtration, washing (toluene); elem. anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1311 - 1320
