in neat (no solvent) byproducts: NOCl; reaction of TeCl2 with liquid N2O4;;
参考文献
Aynsley, E. E.; Watson, R. H.
Journal of the Chemical Society, 1953 , p. 3016 - 3019
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Gmelin Handbook: Te: SVol.B1, 2.2.1.1, page 31 - 34
in neat (no solvent) byproducts: NOCl, NO2Cl; Irradiation (UV/VIS); passing dry N2O4 over the surface of freshly distd. PCl3 cooled at -40 °C and under irradiation with UV light; absortion under formation of a dark red liq.; expelling NO, N2O3, NOCl, NO2Cl;; isolation of liquid products by fractionation; liquid phase containing POCl3, P2O3Cl4 and P4O4Cl10; yield of P2O3Cl4 25 percent, P4O4Cl10 3 percent;;
in neat (no solvent) byproducts: NOCl, NO2Cl, NO; passing dry N2O4 over the surface of freshly distd. PCl3 cooled at -10 °C; absortion under formation of a dark red liq.; expelling NO, N2O3, NOCl, NO2Cl and pptn. of P2O6NCl2; liquid phase contg. POCl3, P2O3Cl4 and a small amount of P4O4Cl10;; isolation of liquid products by fractionation; yield of P2O3Cl4 17 percent and of P4O4Cl10 5 percent;;
