3,7-二甲基-1-辛醇合成路线 （共 89 条）
参考文献
Helvetica Chimica Acta, , vol. 25, p. 1610
参考文献
Chemische Berichte, , vol. 41, p. 1478
反应条件
1-methyl-1H-imidazole in acetonitrile T=20°C; 0.5 h;
参考文献
Gomez, Laura; Garcia-Bosch, Isaac; Company, Anna; Benet-Buchholz, Jordi; Polo, Alfonso; et al.
Angewandte Chemie, International Edition, 2009 , vol. 48, p. 5720 - 5723
Angewandte Chemie, 2009 , vol. 121, p. 5830 - 5833
反应条件
porous p-phenolsulfonic acid-formaldehyde resin T=50°C; 12 h;
参考文献
Minakawa, Maki; Baek, Heeyoel; Yamada, Yoichi M. A.; Han, Jin Wook; Uozumi, Yasuhiro
Organic Letters, 2013 , vol. 15, # 22 p. 5798 - 5801
反应条件
sulfuric acid; hydrogen bromide in water T=120 - 125°C; 3 h;
参考文献
The United States of America as represented by the Secretary of the Air Force; Tan, Loon-Seng; Kannan, Ramamurthi; Dalton, Matthew
Patent: US8471035 B1, 2013 ;
Location in patent: Page/Page column 9; 10 ;
反应条件
1: 92 percent / CCL / diethyl ether / 16 h / 20 - 22 °C 2: 91 percent / KOH / methanol / 1.5 h / 20 - 22 °C 3: 76 percent / 4-Bz-TEMPO, NaBr, NaHCO3 / CH2Cl2 / 5 - 10 °C / electrolysis 4: KOH, Oct4NBr / benzene; H2O / 3 h / 20 - 22 °C View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Kharisov, R. Ya.; Serebryakov, E. P.; Tolstikov, G. A.
Russian Chemical Bulletin, 1993 , vol. 42, # 1 p. 100 - 101
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 1 p. 110 - 112
反应条件
1H-imidazole; iodine; triphenylphosphine in toluene 18 h;
参考文献
ROWETT RESEARCH INSTITUTE
Patent: WO2004/7475 A1, 2004 ;
Location in patent: Page 64 ;
反应条件
potassium dichromate; sulfuric acid
参考文献
Schulze, Agnes; Pagona, Georgia; Giannis, Athanassios
Synthetic Communications, 2006 , vol. 36, # 9 p. 1147 - 1156
反应条件
1: PCC / CH2Cl2 / 2 h / 20 °C
2: 82 percent / diethyl ether / 15 h / 20 °C
3: 1.) O3, O2, 2.) Me2S, 3.) Na2SO4, TsOH*H2O / 1.) CH2Cl2, MeOH, -65 deg C, 2.) -60 deg C, 1h; -15 deg C, 1 h; 0 deg C, 1 h; 20 deg C, 12 h, 3.) benzene, reflux, 1 h
View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Kharisov, R. Ya.; Serebryakov, E. P.; Tolstikov, G. A.
Russian Chemical Bulletin, 1993 , vol. 42, # 1 p. 100 - 101
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 1 p. 110 - 112
反应条件
1: pyridine / 0 °C
2: DMSO / 60 °C
3: NaOH; H2O / ethanol / Heating
View Scheme
参考文献
Wong, Man-Kin; Chung, Nga-Wai; He, Lan; Yang, Dan
Journal of the American Chemical Society, 2003 , vol. 125, # 1 p. 158 - 162
