二(3-甲基丁烷-2-基)硼烷合成路线 （共 13 条）
反应条件
sodium tetrahydroborate; boron trifluoride diethyl etherate in diethylene glycol dimethyl ether
参考文献
Zweifel,G. et al.
Journal of the American Chemical Society, 1962 , vol. 84, p. 190 - 195
反应条件
in tetrahydrofuran T=0°C; 1 h; Inert atmosphere;
参考文献
Ager, David J.; Anderson, Ken; Oblinger, Eric; Shi, Yian; Vanderroest, James
Organic Process Research and Development, 2007 , vol. 11, # 1 p. 44 - 51
反应条件
in tetrahydrofuran T=-10 - 0°C; Inert atmosphere;
参考文献
Sinclair,J.A.; Brown,H.C.
Journal of Organic Chemistry, 1976 , vol. 41, # 6 p. 1078 - 1079
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Brown,H.C. et al.
Journal of Organic Chemistry, 1977 , vol. 42, # 8 p. 1392 - 1398
反应条件
borane-THF T=0°C; 2 h;
参考文献
KDR BIOTECH CO., LTD.; JUNG, Mankil; PAIK, Young-Ki
Patent: WO2005/75491 A1, 2005 ;
Location in patent: Page/Page column 13 ;
反应条件
methyl iodide in tetrahydrofuran byproducts: LiI, CH4; 0°C, 0.5 h;;
参考文献
Singaram, Bakthan; Cole, Thomas E.; Brown, Herbert C.
Organometallics, 1984 , vol. 3, p. 1520 - 1523
反应条件
in 1,4-dioxane N2-atmosphere; slow alkene addn. (0°C), stirring (room temp., 1 h); not isolated, detd. by (11)B NMR spectroscopy;
参考文献
Brown, Herbert C.
Organometallics, 1999 , vol. 18, # 7 p. 1310 - 1317
反应条件
und anschliessend mit wss.Wasserstoffperoxid;
参考文献
Journal of the American Chemical Society, , vol. 81, p. 1512
反应条件
(i) THF, (ii) H2O2, aq. NaOH; Multistep reaction;
参考文献
Zweifel,G. et al.
Journal of the American Chemical Society, 1962 , vol. 84, p. 190 - 195
反应条件
sodium hydroxide; dihydrogen peroxide
参考文献
Brown,H.C.; Zweifel,G.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3222 - 3223
反应条件
sodium hydroxide; dihydrogen peroxide in 1,4-dioxane Oxidation;
参考文献
Brown, Herbert C.; Kanth, Josyula V. B.; Zaidlewicz, Marek
Tetrahedron, 1999 , vol. 55, # 19 p. 5991 - 6000
