tris(dibenzylideneacetone)dipalladium(0) chloroform complex in tetrahydrofuran under exclusion of moisture and air; Ph3SnH, THF and Pd complex (0.01 equiv.) at -78°C added to allylic alcohol (2 equiv.); warmed to room temp. for 16 h under stirring; volatiles removed; sepd. by chromy. (SiO2, gradient petroleum ether-ethyle acetate from 5:1 to 1:1, ethyl acetate); elem. anal.;
参考文献
Christoffers, Jens; Werner, Thomas; Baro, Angelika; Fischer, Peter
Journal of Organometallic Chemistry, 2004 , vol. 689, # 22 p. 3550 - 3555
1: hex-5-ynoic acid With oxalyl dichloride in dichloromethane 2.5 h; Inert atmosphere; 2: With indium(III) chloride in dichloromethane 3 h; Inert atmosphere; 3: allyl alcohol in dichloromethane Inert atmosphere;
参考文献
Hylden, Anne T.; Uzelac, Eric J.; Ostojic, Zeljko; Wu, Ting-Ting; Sacry, Keely L.; Sacry, Krista L.; Xi, Lin; Jones, T. Nicholas
Beilstein Journal of Organic Chemistry, 2011 , vol. 7, p. 1323 - 1326
