1,4-丁二醇二丙烯酸酯合成路线 （共 21 条）
反应条件
1: acrolein With tert-butylhypochlorite in tetrachloromethane T=30°C; 3.33333 h; 2: 4-hydroxybutanol in tetrachloromethane T=25°C; 21.15 h;
参考文献
US2003/216587 A1, ;
Page/Page column 3-4 ;
反应条件
triethylamine; 1,2,3-benzenetriol in benzene T=50°C; 0.5 h;
参考文献
Stenlake; Waigh; Dewar; et al.
European Journal of Medicinal Chemistry, 1981 , vol. 16, # 6 p. 515 - 524
反应条件
in water; Petroleum ether
反应条件
Novozyme 435 in 1,1-dimethylpropan-1-ol T=50°C; 120 h; Inert atmosphereMolecular sieveEnzymatic reaction;
参考文献
Journal of Molecular Catalysis B: Enzymatic, , vol. 62, # 1 p. 80 - 89
反应条件
tetrahydrofuran; copper(ll) bromide; niobium bromide T=200°C; P=36775.4 Torr;
反应条件
triethylamine; hydroquinone in benzene Heating;
参考文献
Journal of pharmaceutical sciences, , vol. 63, # 7 p. 1162 - 1163
反应条件
in acetonitrile T=20°C; electron transfer; Kinetics;
参考文献
Physical Chemistry Chemical Physics, , vol. 2, # 7 p. 1425 - 1430
反应条件
Cu(BF4)2 in water; acetone T=-10 - -5°C; 2 h;
参考文献
Gorbovoi; Baranovskii; Koval'skii; Grishchuk
Russian Journal of General Chemistry, 2002 , vol. 72, # 8 p. 1230 - 1232
反应条件
Cu(BF4)2 in water; acetone addn. of C6H5N2BF4 to 1,4-bis(acryloyloxy)butane, Cu(BF4)2 and NaSCN in aq. acetone (1:2) for 45-60 min; cooling at -10 - -5°C for 2 h; evolution of N2, treatment of residual with Et2O, extn., washing with water, drying with MgSO4, removal of ether, chromy.;
参考文献
Russian Journal of General Chemistry, , vol. 72, # 8 p. 1230 - 1232
反应条件
Cu(BF4)2 in water; acetone addn. of NO2C6H4N2BF4 to 1,4-bis(acryloyloxy)butane, Cu(BF4)2 and NaSCN in aq. acetone (1:2) for 45-60 min; cooling at -10 - -5°C for 2 h; evolution of N2, treatment of residual with Et2O, extn., washing with water, drying with MgSO4, removal of ether, chromy.;
参考文献
Russian Journal of General Chemistry, , vol. 72, # 8 p. 1230 - 1232
